质量水平
检测方案
98%
形式
solid
mp
>300 °C (lit.)
SMILES字符串
[Na+].[O-]S(=O)c1ccccc1
InChI
1S/C6H6O2S.Na/c7-9(8)6-4-2-1-3-5-6;/h1-5H,(H,7,8);/q;+1/p-1
InChI key
CHLCPTJLUJHDBO-UHFFFAOYSA-M
一般描述
当用炔基硒盐处理时，苯亚磺酸钠盐生成 ( Z )-β-烷氧基乙烯基砜 。它通过铑催化的脱硫反应与醛偶联生成酮 。
应用
在有机卤化物与苯亚磺酸钠的反应中，以高级醇或二醇为溶剂，苯亚磺酸钠被用于合成砜 。它也被用于通过铜催化与硼酸和乙烯基砜通过与邻二溴代反应的交叉偶联合成芳基砜。
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Synthesis, 1465-1465 (2007)
Reactions of alkynylselenonium salts with sodium benzenesulfinate.
Kataoka T, et al.
Tetrahedron Letters, 38(10), 1809-1812 (1997)
Tetrahedron, 63, 7667-7667 (2007)
Rhodium-Catalyzed Aerobic Coupling between Aldehydes and Arenesulfinic Acid Salts: A Novel Synthesis of Aryl Ketones.
Rao H, et al.
Advanced Synthesis & Catalysis, 353(10), 1701-1706 (2011)
Pedro Paulo Albuquerque Cavalcanti Albuquerque et al.
The journal of adhesive dentistry, 21(2), 133-141 (2019-04-06)
To determine the degree of conversion (DC), physicochemical properties, and microshear bond strength (µSBS) of experimental self-adhesive resin cements (SARCs) to dentin and yttria-stabilized tetragonal zirconia polycrystal (Y-TZP) ceramic. Dual-curing cements were formulated with UDMA, HEMA, bis-GMA, and TEG-DMA as
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