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Merck
CN

122440

噻蒽

97%

别名:

二苯并二硫代二噁烷

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关于此项目

经验公式(希尔记法):
C12H8S2
化学文摘社编号:
分子量:
216.32
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-197-0
Beilstein/REAXYS Number:
83046
MDL number:
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产品名称

噻蒽, 97%

InChI key

GVIJJXMXTUZIOD-UHFFFAOYSA-N

InChI

1S/C12H8S2/c1-2-6-10-9(5-1)13-11-7-3-4-8-12(11)14-10/h1-8H

SMILES string

S1c2ccccc2Sc3ccccc13

assay

97%

form

solid

bp

364-366 °C (lit.)

mp

151-155 °C (lit.)

solubility

DMF: soluble
H2O: insoluble

Quality Level

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Application

噻蒽已被用于研究蒽、菲和芴的几种固体含氮、硫和氧的杂环衍生物的水溶性。它已被用于测定1-己基-3-甲基咪唑(三氟甲基磺酰基)酰亚胺和超临界二氧化碳中几种含硫芳烃的分配系数

General description

在大孔沸石和中孔铝硅酸盐催化剂存在时,噻蒽可通过液相丁基化反应生成丁基衍生物。在过氧化氢和木质素酶作为来自黄孢原毛平革菌的催化剂存在时,噻蒽经氧化可生成噻蒽单亚砜

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Acid zeolites as catalysts in organic reactions.< i> tert</i>-Butylation of anthracene, naphthalene and thianthrene.
Armengol E, et al.
Applied Catalysis A: General, 149(2), 411-423 (1997)
Pavel Karásek et al.
Journal of chromatography. A, 1140(1-2), 195-204 (2006-12-05)
We report the aqueous solubilities of phenanthrene and several solid three-ring aromatic heterocycles (phenanthridine, acridine, phenazine, thianthrene, phenothiazine, phenoxathiin, phenoxazine, carbazole, dibenzofuran, dibenzothiophene, and 4,6-dimethyldibenzothiophene) at temperatures ranging from 313K to the solute melting point and at a pressure of
Distribution of sulfur-containing aromatics between [hmim][Tf2N] and supercritical CO2: a case study for deep desulfurization of oil refinery streams by extraction with ionic liquids.
Planeta J, et al.
Green Chemistry, 8(1), 70-77 (2006)
R P Schreiner et al.
Applied and environmental microbiology, 54(7), 1858-1860 (1988-07-01)
The oxidation of heterocyclic sulfur compounds reported to be part of the macrostructure of coal and petroleum was investigated. The oxidation of thianthrene solubilized in 10% dimethylformamide to thianthrene monosulfoxide in the presence of hydrogen peroxide was catalyzed by the
Patrick Frank et al.
Inorganic chemistry, 45(24), 9864-9876 (2006-11-23)
Sulfur K-edge X-ray absorption spectroscopy (XAS) was used to characterize the approximately 0.1% sulfur found both in native reticulated vitreous carbon (RVC) foam and in RVC oxidatively modified using 0.2 M KMnO4 in 2 M H2SO4. Sulfur valences and functional

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