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质量水平
方案
97%
表单
solid
沸点
364-366 °C (lit.)
mp
151-155 °C (lit.)
溶解性
DMF: soluble
H2O: insoluble
SMILES字符串
S1c2ccccc2Sc3ccccc13
InChI
1S/C12H8S2/c1-2-6-10-9(5-1)13-11-7-3-4-8-12(11)14-10/h1-8H
InChI key
GVIJJXMXTUZIOD-UHFFFAOYSA-N
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一般描述
在大孔沸石和中孔铝硅酸盐催化剂存在时,噻蒽可通过液相叔丁基化反应生成叔丁基衍生物。在过氧化氢和木质素酶作为来自黄孢原毛平革菌的催化剂存在时,噻蒽经氧化可生成噻蒽单亚砜。
应用
噻蒽已被用于研究蒽、菲和芴的几种固体含氮、硫和氧的杂环衍生物的水溶性。它已被用于测定1-己基-3-甲基咪唑双(三氟甲基磺酰基)酰亚胺和超临界二氧化碳中几种含硫芳烃的分配系数。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Pavel Karásek et al.
Journal of chromatography. A, 1140(1-2), 195-204 (2006-12-05)
We report the aqueous solubilities of phenanthrene and several solid three-ring aromatic heterocycles (phenanthridine, acridine, phenazine, thianthrene, phenothiazine, phenoxathiin, phenoxazine, carbazole, dibenzofuran, dibenzothiophene, and 4,6-dimethyldibenzothiophene) at temperatures ranging from 313K to the solute melting point and at a pressure of
Acid zeolites as catalysts in organic reactions.< i> tert</i>-Butylation of anthracene, naphthalene and thianthrene.
Armengol E, et al.
Applied Catalysis A: General, 149(2), 411-423 (1997)
R P Schreiner et al.
Applied and environmental microbiology, 54(7), 1858-1860 (1988-07-01)
The oxidation of heterocyclic sulfur compounds reported to be part of the macrostructure of coal and petroleum was investigated. The oxidation of thianthrene solubilized in 10% dimethylformamide to thianthrene monosulfoxide in the presence of hydrogen peroxide was catalyzed by the
Distribution of sulfur-containing aromatics between [hmim][Tf2N] and supercritical CO2: a case study for deep desulfurization of oil refinery streams by extraction with ionic liquids.
Planeta J, et al.
Green Chemistry, 8(1), 70-77 (2006)
L L Gershbein
Research communications in chemical pathology and pharmacology, 53(1), 125-128 (1986-07-01)
Male rats were fed a diet supplemented with 0.12% thianthrene or control chow for a period of 10 days after which they were partially hepatectomized, two-thirds of the organ being removed and continued on the diet or switched to the
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