所有图片(1)
About This Item
线性分子式:
NH2CH2CH(OCH3)2
CAS号:
分子量:
105.14
Beilstein:
741868
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
99%
折射率
n20/D 1.417 (lit.)
沸点
135-139 °C/95 mmHg (lit.)
密度
0.965 g/mL at 25 °C (lit.)
官能团
acetal
amine
ether
SMILES字符串
COC(CN)OC
InChI
1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3
InChI key
QKWWDTYDYOFRJL-UHFFFAOYSA-N
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一般描述
氨基乙醛缩二甲醇与砜反应，然后加入所需的哌嗪衍生物进行水解和还原胺化反应，从而产生2-呋喃基[1,2,4]三唑并[1,5-a][1,3,5]三嗪的哌嗪衍生物.
氨基乙醛二甲基缩醛可用作合成各种酰化和磺化氧代烯酰胺（oxyenamide）的合成砌块。
氨基乙醛二甲基缩醛可用作合成各种酰化和磺化氧代烯酰胺（oxyenamide）的合成砌块。
应用
氨基乙醛缩二甲醇被用于开发醛脱氢酶的荧光底物。它被用于制备具有羧基、酯和聚乙二醇等各种官能团的壳聚糖-树枝状大分子杂化物。它被用于从 L-抗坏血酸 合成双环脯氨酸类似物的高效3步合成法，并用于MgClO4 催化的三组分反应，得到α-氨基膦酸盐。
警示用语：
Danger
危险声明
危险分类
Flam. Liq. 3 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
111.2 °F - closed cup
闪点(°C)
44 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Hitoshi Sashiwa et al.
Biomacromolecules, 4(5), 1244-1249 (2003-09-10)
Chitosan-dendrimer hybrids having various functional groups such as carboxyl, ester, and poly(ethylene glycol) groups were prepared successfully using dendrimer acetal by reductive N-alkylation. The synthetic procedure could be accomplished by one-step reaction without organic solvent. The degree of substitution of
R W Storms et al.
Proceedings of the National Academy of Sciences of the United States of America, 96(16), 9118-9123 (1999-08-04)
Because hematopoietic stem cells are rich in aldehyde dehydrogenase (ALDH) activity, we developed a fluorescent substrate for ALDH, termed BODIPY aminoacetaldehyde (BAAA), and tested its potential for isolating primitive human hematopoietic cells. A population of cells with low orthogonal light
Improved synthesis of imidazole-2-carboxaldehyde, imidazole-2-carboxylic acid, and ethyl imidazole-2-carboxylate
Galeazzi, Eduviges and Guzman
The Journal of Organic Chemistry, 60, 1090-1092 (1995)
Stereoselective Synthesis of 2-Oxyenamides
Krieg, Sara-Cathrin and Grimmer
European Journal of Organic Chemistry (2022)
Chi B Vu et al.
Bioorganic & medicinal chemistry letters, 14(19), 4835-4838 (2004-09-03)
Piperazine derivatives of 2-furanyl[1,2,4]triazolo[1,5-a][1,3,5]triazine have recently been shown to be potent and selective adenosine A(2a) receptor antagonists. We now demonstrate that potent and selective A(2a) receptor antagonists could still be obtained when the arylpiperazines are separated from the triazolotriazine core
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