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折射率
n20/D 1.448 (lit.)
密度
0.878 g/mL at 25 °C (lit.)
官能团
allyl
hydroxyl
SMILES字符串
OC(CC=C)C=C
InChI
1S/C6H10O/c1-3-5-6(7)4-2/h3-4,6-7H,1-2,5H2
InChI key
SZYLTIUVWARXOO-UHFFFAOYSA-N
一般描述
1,5-Hexadien-3-ol is the starting reagent for the enantioselective synthesis of (+)-rogioloxepane A. It undergoes Sharpless kinetic resolution and ring-closing metathesis to yield nine membered oxocene.
应用
1,5-Hexadien-3-ol was used in the synthesis of (+)-obtusenyne.
警示用语:
Warning
危险声明
危险分类
Flam. Liq. 3
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
84.2 °F - closed cup
闪点(°C)
29 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Michael T Crimmins et al.
Journal of the American Chemical Society, 125(25), 7592-7595 (2003-06-19)
A total synthesis of the laurencia metabolite (+)-obtusenyne has been completed. The key steps include a Sharpless kinetic resolution and an asymmetric glycolate alkylation to establish the stereogenic centers adjacent to the ether linkage and a ring-closing metathesis reaction to
Yan-Lun Ju et al.
Plant physiology and biochemistry : PPB, 130, 501-510 (2018-08-11)
Grapes are one of the most important fruits because of their economic and nutritional benefits, and grapevines are widely cultivated in arid and semi-arid areas. Therefore, it is critical to study the mechanism by which grapevines respond to water stress.
Induction of rejection of successful allografts of rat islets by donor peritoneal exudate cells.
P E Lacy et al.
Transplantation, 28(5), 415-420 (1979-11-01)
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