推荐产品
质量水平
检测方案
95%
形式
solid
bp
135-136 °C/10 mmHg (lit.)
mp
49-51 °C (lit.)
SMILES字符串
ClC(=O)C12C[C@H]3C[C@H](C[C@H](C3)C1)C2
InChI
1S/C11H15ClO/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2/t7-,8+,9-,11-
InChI key
MIBQYWIOHFTKHD-KJZNFTALSA-N
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一般描述
1-金刚烷羰基氯与异丙基亚磷酸三乙胺反应生成混合酸酐，这是一种用于氢-膦酸盐 DNA 合成的有效封端试剂 。它是金属铟存在下苯甲醚 Friedel–Crafts 酰化反应的良好底物 。
应用
1-金刚烷羰基氯被用于制备高效的胺修饰的寡脱氧核苷酸，用于制备 DNA 微阵列 。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
补充剂危害
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal.
Jang DO, et al.
Tetrahedron Letters, 47(34), 6063-6066 (2006)
Nagendra Kumar Kamisetty et al.
Analytical and bioanalytical chemistry, 387(6), 2027-2035 (2007-01-24)
Amine-modified oligodeoxynucleotides (AMO) are commonly used probe oligodeoxynucleotides for DNA microarray preparation. Two methods are currently used for AMO preparation--use of amine phosphoramidites protected by acid-labile monomethoxytrityl (MMT) groups or alkali-labile trifluoroacetyl (TFA) groups. Because conventional AMO preparation procedures have
Anna K Blakney et al.
Biomacromolecules, 21(6), 2482-2492 (2020-04-07)
Messenger RNA (mRNA) is a promising platform for both vaccines and therapeutics, and self-amplifying RNA (saRNA) is particularly advantageous, as it enables higher protein expression and dose minimization. Here, we present a delivery platform for targeted delivery of saRNA using
Novel activating and capping reagents for improved hydrogen-phosphonate DNA synthesis.
Andrus A, et al.
Tetrahedron Letters, 29(8), 861-864 (1988)
Weiyi Zhao et al.
Journal of controlled release : official journal of the Controlled Release Society, 323, 24-35 (2020-04-14)
Supramolecular hydrogels confer control over structural properties in a reversible, dynamic, and biomimetic fashion. The design of supramolecular hydrogels with an improved structural and functional recapitulation of damaged organs is important for clinical applications. For wound healing management, in particular
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