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Merck
CN

117706

Sigma-Aldrich

苯乙炔

98%

别名:

乙炔苯

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About This Item

线性分子式:
C6H5CCH
CAS号:
分子量:
102.13
Beilstein:
605461
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

17.6 mmHg ( 37.7 °C)

质量水平

检测方案

98%

杂质

<1% 1,4-dioxane

折射率

n20/D 1.549 (lit.)

bp

142-144 °C (lit.)

溶解性

H2O: insoluble
alcohol: miscible
diethyl ether: miscible

密度

0.93 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

C#Cc1ccccc1

InChI

1S/C8H6/c1-2-8-6-4-3-5-7-8/h1,3-7H

InChI key

UEXCJVNBTNXOEH-UHFFFAOYSA-N

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一般描述

苯乙炔是一种芳香有机化合物,常用于Sonogashira偶联反应。苯乙炔在Rh和Pt复合物催化下形成聚苯乙炔

应用

在存在三甲基铝的情况下,末端乙炔可用于将硝基转换到炔基羟基胺。
苯乙炔被用来研究钯催化苯乙炔氧化羰基化反应产物形成机制

警示用语:

Danger

危险分类

Aquatic Chronic 3 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

WGK

WGK 3

闪点(°F)

80.6 °F

闪点(°C)

27 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Tetrahedron Letters, 48, 1457-1457 (2007)
Rhodium and platinum complexes as catalysts for the polymerization of phenylacetylene.
Furlani A, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 24(5), 991-1005 (1986)
Katarina Novakovic et al.
Physical chemistry chemical physics : PCCP, 10(5), 749-753 (2008-02-07)
This paper reports on the influence of oscillations on product selectivity as well as the dynamics of product formation during the palladium-catalysed phenylacetylene oxidative carbonylation reaction in a catalytic system (PdI2, KI, Air, NaOAc in methanol). The occurrence of the
Akira Onoda et al.
Chemical communications (Cambridge, England), 48(78), 9756-9758 (2012-08-25)
Our group recently prepared a hybrid catalyst containing a rhodium complex, Rh(Cp)(cod), with a maleimide moiety at the peripheral position of the Cp ligand. This compound was then inserted into a β-barrel protein scaffold of a mutant of aponitrobindin (Q96C)
Shannon K Yee et al.
ACS nano, 5(11), 9256-9263 (2011-10-21)
The transport properties of a junction consisting of small donor-acceptor molecules bound to Au electrodes are studied and understood in terms of its hybrid donor-acceptor-electrode interfaces. A newly synthesized donor-acceptor molecule consisting of a bithiophene donor and a naphthalenediimide acceptor

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