蒸汽压
17.6 mmHg ( 37.7 °C)
质量水平
检测方案
98%
杂质
<1% 1,4-dioxane
折射率
n20/D 1.549 (lit.)
bp
142-144 °C (lit.)
溶解性
H2O: insoluble
alcohol: miscible
diethyl ether: miscible
密度
0.93 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C#Cc1ccccc1
InChI
1S/C8H6/c1-2-8-6-4-3-5-7-8/h1,3-7H
InChI key
UEXCJVNBTNXOEH-UHFFFAOYSA-N
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一般描述
苯乙炔是一种芳香有机化合物,常用于Sonogashira偶联反应。苯乙炔在Rh和Pt复合物催化下形成聚苯乙炔。
应用
在存在三甲基铝的情况下,末端乙炔可用于将硝基转换到炔基羟基胺。
苯乙炔被用来研究钯催化苯乙炔氧化羰基化反应产物形成机制。
警示用语:
Danger
危险分类
Aquatic Chronic 3 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
80.6 °F
闪点(°C)
27 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Tetrahedron Letters, 48, 1457-1457 (2007)
Rhodium and platinum complexes as catalysts for the polymerization of phenylacetylene.
Journal of Polymer Science Part A: Polymer Chemistry, 24(5), 991-1005 (1986)
Physical chemistry chemical physics : PCCP, 10(5), 749-753 (2008-02-07)
This paper reports on the influence of oscillations on product selectivity as well as the dynamics of product formation during the palladium-catalysed phenylacetylene oxidative carbonylation reaction in a catalytic system (PdI2, KI, Air, NaOAc in methanol). The occurrence of the
Chemical communications (Cambridge, England), 48(78), 9756-9758 (2012-08-25)
Our group recently prepared a hybrid catalyst containing a rhodium complex, Rh(Cp)(cod), with a maleimide moiety at the peripheral position of the Cp ligand. This compound was then inserted into a β-barrel protein scaffold of a mutant of aponitrobindin (Q96C)
ACS nano, 5(11), 9256-9263 (2011-10-21)
The transport properties of a junction consisting of small donor-acceptor molecules bound to Au electrodes are studied and understood in terms of its hybrid donor-acceptor-electrode interfaces. A newly synthesized donor-acceptor molecule consisting of a bithiophene donor and a naphthalenediimide acceptor
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