推荐产品
质量水平
方案
99%
mp
185-188 °C (lit.)
官能团
bromo
SMILES字符串
Oc1cccnc1Br
InChI
1S/C5H4BrNO/c6-5-4(8)2-1-3-7-5/h1-3,8H
InChI key
YKHQFTANTNMYPP-UHFFFAOYSA-N
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应用
2-Bromo-3-pyridinol has been used in the preparation of 2-bromo-4,6-diiodo-3-pyridinol. It has also been used in the total synthesis of pterocellin A by reacting with kojic acid.
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Halogenation of Pyridinols using Bis(sym-collidine)iodine(I) and Bis(sym-collidine)bromine(I) hexafluorophosphate.
Tetrahedron Letters, 38(14), 2467-2470 (1997)
Meaghan M O'Malley et al.
Organic letters, 8(12), 2651-2652 (2006-06-02)
The first total synthesis of pterocellin A (1) was achieved in 10 linear steps from commercially available kojic acid (6) and 2-bromo-3-pyridinol (11) in a convergent sequence. The key constructive steps are a directed lithiation to couple two pyridines and
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