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质量水平
方案
98%
表单
solid
旋光性
[α]20/D −21 to −19°, c = 4 in H2O
光学纯度
ee: 98% (GLC)
反应适用性
reaction type: solution phase peptide synthesis
mp
>300 °C (lit.)
应用
peptide synthesis
SMILES字符串
CC[C@@H](N)C(O)=O
InChI
1S/C4H9NO2/c1-2-3(5)4(6)7/h3H,2,5H2,1H3,(H,6,7)/t3-/m1/s1
InChI key
QWCKQJZIFLGMSD-GSVOUGTGSA-N
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储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Polymers, 12(9) (2020-09-13)
Eight kinds of chiral diacid monomers were prepared with amino acids with different side groups or configurations. Polyester-imides (PEIs) were synthesized from these diacid monomers and diphenol monomers through polycondensation reaction, and the performances and properties were compared with the
Quantification of aminobutyric acids and their clinical applications as biomarkers for osteoporosis.
Communications biology, 3(1), 39-39 (2020-01-24)
Osteoporosis is a highly prevalent chronic aging-related disease that frequently is only detected after fracture. We hypothesized that aminobutyric acids could serve as biomarkers for osteoporosis. We developed a quick, accurate, and sensitive screening method for aminobutyric acid isomers and
Acta crystallographica. Section D, Biological crystallography, 68(Pt 8), 1067-1070 (2012-08-08)
The crystal structure of the PNA (peptide nucleic acid) oligomer H-Lys-HalG-AlaG-HalC-AlaG-HalC-AlaC-Lys-NH(2) (PNA1, amino acids with D-configuration are underlined, Ala = alanyl, Hal = homoalanyl) has been determined by ab initio direct methods and refined against 1.0 Å data. The asymmetric
Organic & biomolecular chemistry, 10(12), 2482-2485 (2012-02-22)
A deracemization method was developed to generate optically pure L-homoalanine from racemic homoalanine using D-amino acid oxidase and ω-transaminase. A whole cell reaction using a biphasic system converted 500 mM racemic homoalanine to 485 mM L-homoalanine (>99% ee).
Nature chemical biology, 3(2), 113-116 (2007-01-16)
Enzymatic incorporation of a halogen atom is a common feature in the biosyntheses of more than 4,500 natural products. Halogenation of unactivated carbon centers in the biosyntheses of several compounds of nonribosomal peptide origin is carried out by a class
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