质量水平
检测方案
98%
形式
solid
bp
181 °C/12 mmHg (lit.)
mp
71-73 °C (lit.)
SMILES字符串
N#CC(c1ccccc1)c2ccccc2
InChI
1S/C14H11N/c15-11-14(12-7-3-1-4-8-12)13-9-5-2-6-10-13/h1-10,14H
InChI key
NEBPTMCRLHKPOB-UHFFFAOYSA-N
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一般描述
将二苯基乙酸酰胺与三氯氧磷脱水,可以得到收率良好的二苯基乙腈 。
应用
二苯基乙腈与 4-溴丁酸乙酯发生无水缩合。随后在碱性介质中水解,用于定量测定 3-氰基-3,3-二苯基丙酸 。
危险声明
预防措施声明
危险分类
Aquatic Chronic 2
WGK
WGK 2
闪点(°F)
Pensky-Martens closed cup
闪点(°C)
Pensky-Martens closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Preparation of diphenylacetonitrile.
Journal of the American Chemical Society, 70(10), 3515-3515 (1948-10-01)
Journal of analytical toxicology, 20(3), 159-164 (1996-05-01)
A sensitive gas chromatographic procedure with nitrogen-phosphorus detection was developed for the quantitative determination of 3-cyano-3,3-diphenylpropionic acid, the acidic metabolite of the narcotic analgesic bezitramide (Burgodin). Gas chromatography with mass spectrometric detection was used for confirmation. An internal standard, 5-cyano-5,5-diphenylvaleric
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