所有图片(2)
别名:
(1S)-(-)-β-蒎烯, (1S,5S)-2(10)-蒎烯, (1S,5S)-6,6-二甲基-2-亚甲基二环[3.1.1]庚烷
经验公式（希尔记法）:
C10H16
CAS号:
分子量:
136.23
Beilstein:
2038282
EC 号:
MDL编号:
UNSPSC代码:
12352212
eCl@ss:
39011007
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽密度
4.7 (vs air)
质量水平
蒸汽压
~2 mmHg ( 20 °C)
检测方案
99%
旋光性
[α]20/D −21°, neat
折射率
n20/D 1.478 (lit.)
bp
165-167 °C (lit.)
mp
−61 °C (lit.)
密度
0.859 g/mL at 25 °C
SMILES字符串
[H][C@]12CCC(=C)[C@]([H])(C1)C2(C)C
InChI
1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9-/m0/s1
InChI key
WTARULDDTDQWMU-IUCAKERBSA-N
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一般描述
(-)-β-蒎烯属于萜烯家族，常作为有机合成中的起始物或中间体。
应用
通过单次给药测试，研究了(-)-β-蒎烯对粉蚧和地中海面蛾的熏蒸活性。在通过气相色谱-质谱法测定 Achillea ligustica 的精油成分时，已将其用作标准品。(-)-β-蒎烯可作为起始原料合成 (1 R ，2 S ,3 R ,5 R )-3-氨基-6,6-二甲基-2-羟基双环 [3.1.1] 庚烷 和 (+)-诺品酮。
警示用语：
Danger
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1
WGK
WGK 3
闪点(°F)
102.2 °F
闪点(°C)
39 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis of (+)-Methyl Phaseate and Its Isomer from (-)-?-Pinene
Takahashi S, et al.
Agricultural and Biological Chemistry, 53(10), 2711-2718 (1989)
Fumigant toxicity of monoterpenoid compounds against the confused flour beetle, Tribolium confusum Jacquelin du Val.(Coleoptera: Tenebrionidae).
Saglam O and Ozder N.
Turkiye Entomoloji Dergisi (Turkish Journal of Entomology), 37(4) (2013)
Chiral terpene auxiliaries. Part 1: Highly enantioselective reduction of ketones with borane catalyzed by an oxazaborolidine derived from (-)-?-pinene
Krzeminski MP and Wojtczak A
Tetrahedron Letters, 46(48), 8299-8302 (2005)
Dual stereoselectivity in the dialkylzinc reaction using (-)-?-pinene derived amino alcohol chiral auxiliaries
Binder CM, et al
The Journal of Organic Chemistry, 74(6), 2337-2343 (2009)
Jean-Jacques Filippi et al.
Journal of agricultural and food chemistry, 54(17), 6308-6313 (2006-08-17)
The essential oil of Achillea ligustica from Corsica was investigated by gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). A total of 82 compounds representing 94.0% of the oil were tentatively identified. The main constituents were the camphane derivatives, representing
Chromatograms
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