111929
4-氯甲苯
98%
别名:
1-氯-4-甲基苯, 1-甲基-4-氯苯, 4-甲基-1-氯苯, 4-甲基氯苯, 4-甲基苯基氯, 对氯甲基苯, 对氯甲苯, 对甲基氯苯
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关于此项目
线性分子式:
CH3C6H4Cl
化学文摘社编号:
分子量:
126.58
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39050207
UNSPSC Code:
12352100
EC Number:
203-397-0
MDL number:
Beilstein/REAXYS Number:
1903635
产品名称
4-氯甲苯, 98%
form
liquid
InChI key
NPDACUSDTOMAMK-UHFFFAOYSA-N
InChI
1S/C7H7Cl/c1-6-2-4-7(8)5-3-6/h2-5H,1H3
SMILES string
Cc1ccc(Cl)cc1
vapor density
4.38 (vs air)
vapor pressure
10 mmHg ( 45 °C)
assay
98%
impurities
≤2% 2-chlorotoluene
refractive index
n20/D 1.52 (lit.)
bp
162 °C (lit.)
mp
6-8 °C (lit.)
density
1.07 g/mL at 25 °C (lit.)
functional group
chloro
Quality Level
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Application
通过将合成的空气通入液体 4-氯噻吩，该产品可用于制备 4-氯噻吩的模型气体。
General description
4-氯三苯和苯基硼酸使用Pd(OAc)2/L•2HX 作为催化剂反应是用于测定双咪唑基（L）配体前体的效率的模型反应。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Flam. Liq. 3 - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
123.8 °F - closed cup
flash_point_c
51 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Palladium-bisimidazol-2-ylidene complexes as catalysts for general and efficient Suzuki cross-coupling reactions of aryl chlorides with arylboronic acids.
Zhang C and Trudell ML.
Tetrahedron Letters, 41(5), 595-598 (2000)
Organic pollutants treatment in gas phase by using electron beam generated non-thermal plasma reactor.
Sun, Y, et al.
Chem. Listy, 102(16), s1524-s1528 (2008)
Mannar R Maurya et al.
Dalton transactions (Cambridge, England : 2003), (32)(32), 4220-4232 (2008-08-07)
3-Formylsalicylic acid (Hfsal), covalently bound to chloromethylated polystyrene (PS) and cross-linked with 5% divinylbenzene reacts with d,l-alanine and l-isoleucine to give the Schiff-base tridentate ligands PS-H(2)fsal-d,l-Ala and PS-H(2)fsal-l-Ile, respectively. These anchored ligands upon reaction with VOSO(4) and Cu(CH(3)COO)(2).H(2)O form the
Eric R Strieter et al.
Journal of the American Chemical Society, 125(46), 13978-13980 (2003-11-13)
A comparative kinetic examination of catalyst systems based on several monophosphinobiaryl ligands is reported. The bulk of the phosphine ligand controls the catalytic activity and the rate of catalyst activation with the catalyst based on 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl providing the greatest activity
Ya-Jun Liu et al.
Physical chemistry chemical physics : PCCP, 7(23), 3938-3942 (2005-12-07)
Equilibrium geometries and vibrational frequencies of the ground and some excited states of p-chlorotoluene were calculated by the complete active space self-consistent field (CASSCF) method. Multi-reference CASSCF second order perturbation theory (MSCASPT2) calculations were performed on the vertical excitation energies
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