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Merck
CN

111848

Sigma-Aldrich

反式-β-甲基苯乙烯

99%

别名:

反-β-甲基苯乙烯, 反式丙烯苯

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About This Item

线性分子式:
C6H5CH=CHCH3
CAS号:
分子量:
118.18
Beilstein:
1361672
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

99%

包含

20 ppm 3,5-di-tert-butylcatechol as inhibitor

折射率

n20/D 1.550 (lit.)

bp

175 °C (lit.)

密度

0.911 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

C\C=C\c1ccccc1

InChI

1S/C9H10/c1-2-6-9-7-4-3-5-8-9/h2-8H,1H3/b6-2+

InChI key

QROGIFZRVHSFLM-QHHAFSJGSA-N

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一般描述

该产品在较高温度下存在潜在放热危害

应用

反式-β-甲基苯乙烯用于 Povarov 反应的乙二酸类似物制备外色满
反式-β-甲基苯乙烯用于氧化剂溶液与二氯甲烷溶液的环氧化反应,其中镍用作催化剂,苄基三丁基溴化铵用作相转移剂

警示用语:

Danger

危险分类

Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 2

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Rivka R R Taylor et al.
The Journal of organic chemistry, 78(4), 1404-1420 (2012-12-13)
An oxa analogue of the well-known Povarov reaction has been developed for the synthesis of 3,4-dihydrobenzopyrans (chromans). The reaction involves the formal inverse electron demand [4 + 2] cycloaddition reaction of in situ-generated cationic aryl 2-oxadiene oxocarbenium ions with alkenes.
S Y Lin et al.
Journal of hazardous materials, 161(1), 330-335 (2008-05-20)
According to literature and our research, the styrene polymerization mechanism is identified by alpha-methylstyrene (AMS). This study investigated the basic exothermic behavior of styrene and its major derivatives, AMS, and trans-beta-methylstyrene (TBMS), by two calorimeters, differential scanning calorimetry (DSC) and
(Salen)nickel-Catalysed Epoxidations in the Homogeneous and Heterogeneous Phase: The Implications of Oxygen on the Efficiency and Product Selectivity.
Ferreira R, et al.
European Journal of Inorganic Chemistry, 2005(21), 4272-4279 (2005)

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