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一般描述
反式-1,3-戊二烯光谱通过传统和腔内激光光声光谱测试法记录在 5000-17500 cm (-1) 区域。可采用基于 Diels-Alder 反应的分光光度法测定它。在该反应中,顺式 1,3-二烯和四氰基乙烯(TCNE)与芳香族 TCNE pi 络合物反应 。
应用
- Hydroxyl radical reactions with diolefins in atmospheric and combustion environments: This study provides insights into the reactions of hydroxyl radicals with diolefins such as trans-1,3-Pentadiene, highlighting their significance in both atmospheric chemistry and combustion processes. This research helps in understanding the reactive pathways and kinetics that could inform both environmental and industrial applications of trans-1,3-Pentadiene (Khaled et al., 2019).
警示用语:
Danger
危险分类
Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
5.0 °F - closed cup
闪点(°C)
-15 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
监管及禁止进口产品
The journal of physical chemistry. A, 110(3), 913-920 (2006-01-20)
The room-temperature vapor-phase overtone spectra of cis- and trans-1,3-pentadiene (piperylene) have been recorded in the 5000-17500 cm(-1) region with the use of conventional and intracavity laser photoacoustic spectroscopy. The presence of five nonequivalent olefinic CH bonds and one methyl group
Talanta, 20(11), 1085-1096 (1973-11-01)
An indirect spectrophotometric method, based on the rapid Diels-Alder reaction between cisoid 1,3-dienes and tetracyanoethylene (TCNE) and the destruction of an aromatic-TCNE pi-complex, was developed to determine eleven 1,3-dienes in the 0.05-1.00 x 10(-3)M range. These dienes were: cyclopentadiene; 1,3-cyclohexadiene;
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