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质量水平
方案
99%
折射率
n20/D 1.429 (lit.)
沸点
134-137 °C (lit.)
密度
0.834 g/mL at 25 °C (lit.)
官能团
allyl
hydroxyl
SMILES字符串
OCCCC=C
InChI
1S/C5H10O/c1-2-3-4-5-6/h2,6H,1,3-5H2
InChI key
LQAVWYMTUMSFBE-UHFFFAOYSA-N
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一般描述
在溶液中，以 HATU 为偶联剂， 4-戊烯-1-醇与线性肽的 C 末端形成酯键。
应用
4-戊烯-1-醇可作为反应物，与氯磺酰异氰酸酯（142662）反应，制备氨基磺酸酯。所得衍生酯在Cu作为催化剂存在的条件下，进行对映选择性分子内氮杂环丙烷化反应。以4-戊烯-1-醇作为催化剂，碳酸氢盐为助催化剂，研究氧代-二过氧钨酸盐 (VI) 配合物对烯烃的环氧化反应。
Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(VI) complex as catalyst.
Maiti SK, et al.
New. J. Chem., 30(3), 479-489 (2006)
Enantioselective Intramolecular Copper-Catalyzed Aziridination of Sulfamates
Audrey Esteoule.et al.
Synthesis, 1251-1251 (2007)
Marina D Rvovic et al.
Journal of molecular modeling, 17(6), 1251-1257 (2010-08-17)
The mechanism of phenylselenoetherification of pent-4-en-1-ol using some bases (pyridine, triethylamine, quinoline, 2,2'-bipyridine) as catalyst was examined through studies of kinetics of the cyclization, by UV-VIS spectrophotometry. It was demonstrated that the intramolecular cyclization is facilitated in the presence of
Stefania Terracciano et al.
Bioorganic & medicinal chemistry, 16(13), 6580-6588 (2008-05-30)
In the recent years, we focused our attention on the cyclodepsipeptide Jaspamide 1, an interesting marine metabolite, possessing a potent inhibitory activity against breast and prostate cancer, as a consequence of its ability to disrupt actin cytoskeleton dynamics. Although its
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