推荐产品
蒸汽压
6.87 psi ( 20 °C)
质量水平
检测方案
97%
折射率
n20/D 1.419 (lit.)
bp
40-41 °C (lit.)
mp
−148 °C (lit.)
密度
0.694 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(C)=C=C
InChI
1S/C5H8/c1-4-5(2)3/h1H2,2-3H3
InChI key
PAKGDPSCXSUALC-UHFFFAOYSA-N
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应用
3-Methyl-1,2-butadiene (1,1-dimethylallene) has been used to study the photo-induced reaction of 1,1-dimethylallene with the cyanoarenes 1,2,4,5-tetracyanobenzene, 1,4-dicyanobenzene and 1,4-dicyanonaphthalene in the presence of methanol as nucleophile.
警示用语：
Danger
危险分类
Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
10.4 °F
闪点(°C)
-12 °C
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
The electron transfer photochemistry of allenes with cyanoarenes. Photochemical nucleophile?olefin combination, aromatic substitution (photo-NOCAS) and related reactions.
Mangion D, et al.
J. Chem. Soc. Perkin Trans. II, 1, 48-60 (2001)
Shaochen Zhang et al.
Science (New York, N.Y.), 364(6435), 45-51 (2019-04-06)
Accessing enantiomerically enriched amines often demands oxidation-state adjustments, protection and deprotection processes, and purification procedures that increase cost and waste, limiting applicability. When diastereomers can be formed, one isomer is attainable. Here, we show that nitriles, largely viewed as insufficiently
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