110019
二异丙胺
99%, liquid
别名:
DIPA
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关于此项目
线性分子式:
(CH3)2CHNHCH(CH3)2
化学文摘社编号:
分子量:
101.19
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
203-558-5
Beilstein/REAXYS Number:
605284
MDL number:
产品名称
二异丙胺, 99%
InChI key
UAOMVDZJSHZZME-UHFFFAOYSA-N
InChI
1S/C6H15N/c1-5(2)7-6(3)4/h5-7H,1-4H3
SMILES string
CC(C)NC(C)C
vapor density
3.5 (vs air)
vapor pressure
50 mmHg ( 20 °C)
assay
99%
form
liquid
autoignition temp.
599 °F
expl. lim.
8.5 %
availability
available only in EU
Quality Level
refractive index
n20/D 1.392 (lit.)
bp
84 °C (lit.)
mp
−61 °C (lit.)
solubility
water: soluble 110 g/L at 25 °C
density
0.722 g/mL at 25 °C (lit.)
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
7.8 °F - closed cup
flash_point_c
-13.45 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Reaction of amines and acid catalysts. IV. Kinetics and mechanism of olefin formation from triethylamine and diisopropylamine on ?-alumina.
Hogan P and Pasek J.
Collection of Czechoslovak Chemical Communications, 38(5), 1513-1521 (1973)
Synthesis of high carbon materials from acetylenic precursors. Preparation of aromatic monomers bearing multiple ethynyl groups.
Neenan TX and Whitesides GM.
The Journal of Organic Chemistry, 53(11), 2489-2496 (1988)
Songping Liao et al.
Journal of the American Chemical Society, 125(49), 15114-15127 (2003-12-05)
Lithium diisopropylamide-mediated lithiations of N-alkyl ketimines derived from cyclohexanones reveal that simple substitutions on the N-alkyl side chain and the 2-position of the cyclohexyl moiety afford a 60,000-fold range of rates. Detailed rate studies implicate monosolvated monomers at the rate-limiting
Diisopropylamide and TMP turbo-Grignard reagents: a structural rationale for their contrasting reactivities.
David R Armstrong et al.
Angewandte Chemie (International ed. in English), 49(18), 3185-3188 (2010-03-31)
Kanwal Jit Singh et al.
Journal of the American Chemical Society, 128(42), 13753-13760 (2006-10-19)
Structural and mechanistic studies of the lithium diisopropylamide (LDA)-mediated anionic Fries rearrangements of aryl carbamates are described. Substituents at the meta position of the arene (H, OMe, F) and the dialkylamino moiety of the carbamate (Me(2)N, Et(2)N, and i-Pr(2)N) markedly
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