109835
2-甲基吡啶
98%
别名:
2-甲基吡啶, α-甲基吡啶, NSC 3409
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关于此项目
经验公式（希尔记法）:
C6H7N
化学文摘社编号:
分子量:
93.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-643-7
Beilstein/REAXYS Number:
104581
MDL number:
产品名称
2-甲基吡啶, 98%
InChI key
BSKHPKMHTQYZBB-UHFFFAOYSA-N
InChI
1S/C6H7N/c1-6-4-2-3-5-7-6/h2-5H,1H3
SMILES string
Cc1ccccn1
vapor density
3.2 (vs air)
vapor pressure
10 mmHg ( 24.4 °C)
assay
98%
autoignition temp.
995 °F
expl. lim.
8.6 %
refractive index
n20/D 1.500 (lit.)
bp
128-129 °C (lit.)
mp
−70 °C (lit.)
solubility
H2O: freely soluble
alcohol: miscible
diethyl ether: miscible
density
0.943 g/mL at 25 °C (lit.)
Quality Level
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Application
2-甲基吡啶 (2-Picoline，2-Methylpyridine) 用于傅里叶变换离子回旋共振质谱研究三甲基异咯嗪的电子和质子转移反应 。
2-甲基吡啶在合成途径中用于生成脱芳香化、烯丙基化和 C-H 键活化的吡啶衍生物 。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1C - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
84.2 °F - closed cup
flash_point_c
29 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
J Christian Lennox et al.
The journal of physical chemistry. B, 121(46), 10530-10542 (2017-11-14)
A polypyridyl ruthenium complex with fluorinated bipyridine ligands and a covalently bound tyrosine moiety was synthesized, and its photo-induced proton-coupled electron transfer (PCET) reactivity in acetonitrile was investigated with transient absorption spectroscopy. Using flash-quench methodology with methyl viologen as an
Tianlan Zhang et al.
The journal of physical chemistry. A, 117(44), 11136-11141 (2013-09-07)
Examination of electron transfer and proton transfer reactions of lumiflavin and proton transfer reactions of the lumiflavin radical anion by Fourier transform ion cyclotron resonance mass spectrometry is described. From the equilibrium constant determined for electron transfer between 1,4-naphthoquinone and
Phillip Jochmann et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(43), 12115-12122 (2011-09-10)
A facile and general synthetic pathway for the production of dearomatized, allylated, and C-H bond activated pyridine derivatives is presented. Reaction of the corresponding derivative with the previously reported reagent bis(allyl)calcium, [Ca(C(3)H(5))(2)] (1), cleanly affords the product in high yield.
Malcolm E Tessensohn et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 18(16), 2250-2257 (2017-06-14)
The voltammetric behavior of 2,3,5,6-tetramethyl-1,4-phenylenediamine was found to be able to differentiate the hydrogen acceptor abilities of electroinactive pyridine compounds in acetonitrile. Weak and strong hydrogen acceptors were distinguished through the onset of a third oxidation process that came about
Nikolaos Kritikos et al.
Journal of chromatography. A, 1403, 70-80 (2015-06-06)
In the current study, quantitative structure-retention relationships (QSRR) were constructed based on data obtained by a LC-(ESI)-QTOF-MS/MS method for the determination of amino acid analogues, following their derivatization via chloroformate esters. Molecules were derivatized via n-propyl chloroformate/n-propanol mediated reaction. Derivatives
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