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Merck
CN

109533

Sigma-Aldrich

衣康酸二甲酯

97%

别名:

2-(Methylene)butanedioic dimethyl ester

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About This Item

线性分子式:
CH3O2CCH2C(=CH2)CO2CH3
CAS号:
分子量:
158.15
Beilstein:
386674
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

solid

bp

208 °C (lit.)

mp

37-41 °C (lit.)

密度

1.124 g/mL at 25 °C (lit.)

SMILES字符串

COC(=O)CC(=C)C(=O)OC

InChI

1S/C7H10O4/c1-5(7(9)11-3)4-6(8)10-2/h1,4H2,2-3H3

InChI key

ZWWQRMFIZFPUAA-UHFFFAOYSA-N

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一般描述

衣康酸二甲酯在Rh(I)催化下进行对映选择性加氢反应,在(1,2-二芳基膦基氧基)环己烷的芳环上选择适当的取代基可提高反应的活性。.

应用

衣康酸二甲酯可用于全同立构聚(丙烯)的官能化。它可用于聚酯:聚(异山梨醇衣康酸酯)和聚(异山梨醇衣康酸酯-共-琥珀酸酯)的交联

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Skin Irrit. 2 - Skin Sens. 1B

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Gloves, type N95 (US)


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T. V. RajanBabu et al.
The Journal of organic chemistry, 64(10), 3429-3447 (2001-10-25)
Enantioselectivity of Rh(I)-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives and dimethyl itaconate can be enhanced by the appropriate choice of substituents on the aromatic rings of vicinal diarylphosphinites derived from carbohydrates as well as trans-cyclohexane-1,2-diol. For example, the use of
Polymers with shape memory effect from renewable resources: crosslinking of polyesters based on isosorbide, itaconic acid and succinic acid.
Goerz O and Ritter H.
Polymer International, 62(5), 709-712 (2013)
M Sendra et al.
Fish & shellfish immunology, 106, 645-655 (2020-08-18)
Immune-responsive gene 1 (irg1) is a gene that is well-conserved among different taxa and is highly expressed in the mussel Mytilus galloprovincialis at the constitutive level. The expression of this gene increases after a bacterial infection, primarily in haemocytes. irg1
Modification of poly (propylene) through grafting with dimethyl itaconate in solution.
Yazdani-Pedram M, et al.
Macromolecular Chemistry and Physics, 199(11), 2495-2500 (1998)
André M Charbonneau et al.
Materials (Basel, Switzerland), 13(21) (2020-11-01)
The egg yolk plasma (EYP)-a translucent fraction of the egg yolk (EY) obtained by centrifugation-was tested as a developmentally encouraging, cost-effective, biomaterial for salivary gland (SG) tissue engineering. To find optimal incubating conditions for both the human NS-SV-AC SG acinar

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