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Merck
CN

109207

Sigma-Aldrich

2-甲基-2-丙硫醇

99%

别名:

TBM, 叔丁硫醇

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About This Item

线性分子式:
(CH3)3CSH
CAS号:
分子量:
90.19
Beilstein:
505947
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

3.1 (vs air)

质量水平

蒸汽压

303.5 mmHg ( 37.7 °C)

检测方案

99%

折射率

n20/D 1.423 (lit.)

bp

62-65 °C (lit.)

mp

-0.5 °C (lit.)

溶解性

H2O: slightly soluble
alcohol: very soluble
diethyl ether: very soluble

密度

0.8 g/mL at 25 °C (lit.)

SMILES字符串

CC(C)(C)S

InChI

1S/C4H10S/c1-4(2,3)5/h5H,1-3H3

InChI key

WMXCDAVJEZZYLT-UHFFFAOYSA-N

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一般描述

2-甲基-2-丙硫醇与 3-异噻唑啉酮发生开环亲核反应,反应动力学研究表明,反应在巯基中为二级反应,整体为三级反应

应用

使用程序升温反应、高分辨率电子能量损失和X射线光电子能谱,将2-甲基-2-丙硫醇用于Mo(110)上的2-甲基-2-丙硫醇反应。在偏氯乙烯与丙烯酸甲酯的可逆加成-断裂链转移共聚反应中,被用于链转移剂的合成

警示用语:

Danger

危险声明

危险分类

Aquatic Chronic 2 - Flam. Liq. 2 - Skin Sens. 1B

WGK

WGK 3

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

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Arjan van Laarhoven et al.
The Journal of infectious diseases, 215(7), 1029-1039 (2017-04-19)
Damaging inflammation is thought to contribute to the high morbidity and mortality of tuberculous meningitis (TBM), but the link between inflammation and outcome remains unclear. We performed prospective clinical and routine laboratory analyses of a cohort of adult patients with
Christian Ledig et al.
Scientific reports, 8(1), 11258-11258 (2018-07-28)
Magnetic resonance (MR) imaging is a powerful technique for non-invasive in-vivo imaging of the human brain. We employed a recently validated method for robust cross-sectional and longitudinal segmentation of MR brain images from the Alzheimer's Disease Neuroimaging Initiative (ADNI) cohort.
Qunxi Dong et al.
NeuroImage. Clinical, 22, 101744-101744 (2019-03-11)
Apolipoprotein E (APOE) e4 is the major genetic risk factor for late-onset Alzheimer's disease (AD). The dose-dependent impact of this allele on hippocampal volumes has been documented, but its influence on general hippocampal morphology in cognitively unimpaired individuals is still
Laura Seynaeve et al.
NeuroImage. Clinical, 21, 101657-101657 (2019-01-21)
Transcranial magnetic stimulation (TMS) is a useful technique to help localize motor function prior to neurosurgical procedures. Adequate modelling of the effect of TMS on the brain is a prerequisite to obtain reliable data. Twelve patients were included with perirolandic
Ursula K Rohlwink et al.
Nature communications, 10(1), 3767-3767 (2019-08-23)
Tuberculous meningitis (TBM) is the most severe form of TB with high rates of mortality and morbidity. Here we conduct RNA-sequencing on whole blood as well as on ventricular and lumbar cerebrospinal fluid (CSF) of pediatric patients treated for TBM.

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