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等级
produced by Wacker Chemie AG, Burghausen, Germany
质量水平
方案
≥96.0% (GC)
包含
~0.1% Drapex 39 as stabilizer
折射率
n20/D 1.432 (lit.)
沸点
120 °C (lit.)
溶解性
H2O: soluble 10 parts
alcohol: miscible
chloroform: miscible
diethyl ether: miscible
密度
1.162 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(=O)CCl
InChI
1S/C3H5ClO/c1-3(5)2-4/h2H2,1H3
InChI key
BULLHNJGPPOUOX-UHFFFAOYSA-N
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一般描述
氯丙酮与L-脯氨酸酰胺催化的 4-硝基苯甲醛发生直接羟醛反应。它与羧酸反应形成酯衍生物。
应用
氯丙酮用于氯丙酮的微生物不对称还原合成手性 1,2-环氧丙烷。它用于通过气相色谱分析酸。它还用于和 1-((3-(萘并[2,1-b]呋喃-2-基)-1-苯基-1H-吡唑-4-基)亚甲基)-2-苯腙反应合成甲基噻唑衍生物。
其他说明
可根据要求提供批量价格
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
95.0 °F - closed cup
闪点(°C)
35 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Ashraf H F Abd El-Wahab et al.
Molecules (Basel, Switzerland), 16(1), 307-318 (2011-01-27)
Vilsmeier formylation of 2-(1-phenylhydrazonoethyl)naphtho[2,1-b]furan (2) gave 3-naphtho[2,1-b]furan-2-yl-1-phenyl-1H-pyrazole-4-carbaldehyde (3), which was reacted with C- and N-nucleophiles to afford naphthofuranpyrazol derivatives 4-8. Treatment of 2-[(3-(naphtho[2,1-b]furan-2-yl)-1-phenyl-1H-pyrazol-4-yl)methylene]-malononitrile (4a) with reactants having active hydrogen and Et₃N gave the corresponding pyrazoline, pyran and chromene addition product
Analysis of carboxylic acids by gas chromatography. Derivatisation using chloroacetone.
McCalley DV, et al.
Chromatographia, 18(6), 309-312 (1984)
Synthesis of optically pure 1, 2-epoxypropane by microbial asymmetric reduction of chloroacetone.
Weijers CAGM, et al.
Applied Microbiology and Biotechnology, 38(3), 297-300 (1992)
L-Proline amide-catalyzed direct asymmetric aldol reaction of aldehydes with chloroacetone.
He L, et al.
Tetrahedron, 62(2), 346-351 (2006)
Luis F Garcia-Alles et al.
Biochemistry, 43(41), 13037-13045 (2004-10-13)
Dihydroxyacetone (Dha) kinases are a sequence-conserved family of enzymes, which utilize two different phosphoryldonors, ATP in animals, plants, and some bacteria, and a multiphosphoprotein of the phosphoenolpyruvate carbohydrate phosphotransferase system (PTS) in most bacteria. Here, we compare the PTS-dependent kinase
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