等级
produced by Wacker Chemie AG, Burghausen, Germany
质量水平
检测方案
≥98% (GC)
bp
254 °C/1013 hPa (lit.)
溶解性
H2O: slightly soluble 1 g/L at 20 °C
密度
0.871 g/mL at 20 °C (lit.)
SMILES字符串
CCCCCCCCCCCC(=O)OC=C
InChI
1S/C14H26O2/c1-3-5-6-7-8-9-10-11-12-13-14(15)16-4-2/h4H,2-3,5-13H2,1H3
InChI key
GLVVKKSPKXTQRB-UHFFFAOYSA-N
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一般描述
Vinyl laurate is a clear, colorless to light yellow colored liquid. The flash point is 125°C. It forms aqueous colloidal microgel by copolymerization with N-isopropylacrylamide. The enzymatic acylation of Avicel cellulose with vinyl laurate, a solvent free reaction system, was studied.
应用
Vinyl laurate was used in the synthesis of laurate and stearate esters of corn starch. It was used as the acyl donor during synthesis of sucrose laurate esters catalyzed by Bacillus pseudofirmus AL-89 . Vinyl laurate was also used in the preparation of chirally deuterated benzyl chlorides.
其他说明
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WGK
WGK 1
个人防护装备
Eyeshields, Gloves
Synthesis of sucrose laurate using a new alkaline protease.
Tetrahedron Asymmetry, 14(6), 667-673 (2003)
Bioresource technology, 102(2), 1378-1382 (2010-10-05)
Cellulose esters are an important class of functional biopolymers with great interest in the chemical industry. In this work the enzymatic acylation of Avicel cellulose with vinyl propionate, vinyl laurate and vinyl stearate, has been performed successfully in a solvent
Synthesis of higher fatty acid starch esters using vinyl laurate and stearate as reactants.
Starch/Staerke, 60(12), 667-675 (2008)
Novel gelling behavior of poly (N-isopropylacrylamide-co-vinyl laurate) microgel dispersions.
Langmuir, 18(16), 6025-6030 (2002)
Journal of labelled compounds & radiopharmaceuticals, 56(1), 6-11 (2013-11-29)
Chirally deuterated benzyl chlorides were prepared using novel, general hexachloroacetone/polymer-supported triphenylphosphine treatment of chirally deuterated benzyl alcohols. Doubly labeled protected tyrosine was obtained in 62% yield with 86% de at the α-carbon and 82% de at the β-carbon. Key in
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