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质量水平
方案
99%
折射率
n20/D 1.410 (lit.)
沸点
126-127 °C (lit.)
密度
1.294 g/mL at 25 °C (lit.)
SMILES字符串
COS(=O)OC
InChI
1S/C2H6O3S/c1-4-6(3)5-2/h1-2H3
InChI key
BDUPRNVPXOHWIL-UHFFFAOYSA-N
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一般描述
亚硫酸二甲酯是一种驱虫剂，并且通过实验确定其为诱变剂。
应用
通过基质分离傅里叶变换红外光谱研究了亚硫酸二甲酯的构象和振动光谱，并研究了其构象选择性聚集。它可以用于有机合成。
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
100.4 °F - closed cup
闪点(°C)
38 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Conformational cooling and conformation selective aggregation in dimethyl sulfite isolated in solid rare gases.
Borba A, et al.
Journal of Molecular Structure, 794(1), 196-203 (2006)
K Nagarajan et al.
Chemical communications (Cambridge, England), (18)(18), 1786-1787 (2002-09-25)
pH dependent reactivity differences of dimethylsulfite towards the title complex 1 demonstrate the crucial need of oxo-anionic coordination of sulfite to the molybdenum centre of 1 in the model reductive half reaction of sulfite oxidase.
M S Brody et al.
Biochimica et biophysica acta, 1253(2), 133-135 (1995-12-06)
We have undertaken a steady-state and rapid kinetic study of the reaction of enzyme with sulfite and dimethylsulfite. Methylation of sulfite results in a significant increase in Km and Kd for the substrate in the course of steady-state and rapid
Ana Borba et al.
The journal of physical chemistry. A, 109(16), 3578-3586 (2006-07-15)
The preferred conformations of dimethyl sulfite and their vibrational spectra were studied by matrix-isolation Fourier transform infrared spectroscopy and theoretical methods (density functional theory (DFT) and Moller-Plesset (MP2), with basis sets of different sizes, including the quadruple-zeta, aug-cc-pVQZ basis). Five
Lin Feng et al.
Huan jing ke xue= Huanjing kexue, 31(2), 345-351 (2010-04-16)
A pilot-scale subsurface constructed wetland wastewater treatment system was sampled for one year to study the effects of bed aspect ratio, substrate medium size, water depth, HLR (hydraulic loading rate) and temperature (season) on removal of volatile alkylsulfides such as
商品
Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.
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