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Merck
CN

108413

Sigma-Aldrich

氯乙酸甲酯

99%

别名:

Chloroacetic acid methyl ester, Methyl 2-chloroacetate

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About This Item

线性分子式:
ClCH2COOCH3
CAS号:
分子量:
108.52
Beilstein:
506255
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

3.8 (vs air)

质量水平

蒸汽压

10 mmHg ( 25 °C)
5.25 mmHg ( 20 °C)

检测方案

99%

自燃温度

869 °F

expl. lim.

18.5 %

折射率

n20/D 1.422 (lit.)

bp

130 °C/740 mmHg (lit.)

mp

−33 °C (lit.)

溶解性

H2O: insoluble
alcohol: miscible
diethyl ether: miscible

密度

1.238 g/mL at 25 °C (lit.)

SMILES字符串

COC(=O)CCl

InChI

1S/C3H5ClO2/c1-6-3(5)2-4/h2H2,1H3

InChI key

QABLOFMHHSOFRJ-UHFFFAOYSA-N

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一般描述

氯乙酸甲酯作为萃取溶剂,通过毛细管电泳分离,利用耦合液-液半微萃取和胶束电动色谱分离中性化合物,提高了浓度 。再生用于合成碳酸二甲酯的 PdCl 2-CuCl2/活性炭催化剂

应用

以氯乙酸甲酯为原料制备氯化(羧甲基)三甲基铵。可用于合成-(碳乙氧基甲氧基)杯 [8] 芳烃

警示用语:

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

116.6 °F

闪点(°C)

47 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Nonionogenic star-shaped calix [8] arenes: Synthesis and ionophore properties.
Ten'kovtsev AV and Razina AB.
Russian Journal of Applied Chemistry, 82(9), 1615-1619 (2009)
A W Lloyd et al.
The Journal of pharmacy and pharmacology, 46(9), 704-707 (1994-09-01)
Glycinebetaine and N-modified betaines have been previously shown to be effective at reducing leakage from liposomes on freeze-thaw procedures. This study involved the preparation of a series of other modified betaines and the comparison of their abilities to reduce leakage
The effects of promoters on catalytic properties and deactivation-regeneration of the catalyst in the synthesis of dimethyl carbonate.
Ruixia J, et al.
Applied Catalysis A: General, 238(1), 131-139 (2003)
Tianlin Wang et al.
Journal of chromatography. A, 1147(1), 105-110 (2007-03-03)
This paper reports the use of methyl chloroacetate (MCA) as an extraction solvent for coupling liquid-liquid semimicroextraction (LLsME) with micellar electrokinetic chromatography (MEKC) through on-capillary decomposition for the separation of neutral compounds with concentration enhancement. Alkylphenones of C(8), C(10) and
Daniele Tedesco et al.
Chirality, 27(12), 914-918 (2015-10-09)
Caffeic acid-derived polyethers are a class of natural products isolated from the root extracts of comfrey and bugloss, which are endowed with intriguing pharmacological properties as anticancer agents. The synthesis of new polyether derivatives is achieved through ring-opening polymerization of

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