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Merck
CN

108030

Sigma-Aldrich

3-氯-2-甲基-1-丙烯

technical grade, 90%

别名:

β-甲基烯丙基氯

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About This Item

线性分子式:
CH2=C(CH3)CH2Cl
CAS号:
分子量:
90.55
Beilstein:
878160
EC 号:
MDL编号:
UNSPSC代码:
12352100
eCl@ss:
39050134
PubChem化学物质编号:
NACRES:
NA.22

等级

technical grade

质量水平

蒸汽密度

3.12 (vs air)

蒸汽压

102 mmHg ( 20 °C)

检测方案

90%

自燃温度

899 °F

包含

~600 ppm BHT as stabilizer

expl. lim.

9.3 %

折射率

n20/D 1.427 (lit.)

bp

71-72 °C (lit.)

mp

−80 °C (lit.)

溶解性

H2O: insoluble
acetone: soluble
chloroform: soluble
diethyl ether: soluble
ethanol: soluble

密度

0.925 g/mL at 20 °C (lit.)

储存温度

2-8°C

SMILES字符串

CC(=C)CCl

InChI

1S/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3

InChI key

OHXAOPZTJOUYKM-UHFFFAOYSA-N

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一般描述

3-Chloro-2-methyl-1-propene is the reactant for the synthesis of cyclobutanone.

应用

3-Chloro-2-methyl-1-propene was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate. It was used to study cationic polymerization of 3-Chloro-2-methyl-1-propene using using AICI3 and A3IBr, as initiators.

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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访问文档库

The cationic polymerization of 3-chloro-2-methyl-1-propene.
Marek M, et al.
Makromol. Chem., 187(10), 2337-2344 (1986)
Cyclobutanone from Methylenecyclopropane via Oxaspiropentane.
Salaun JRJC and Conia JM.
Organic Syntheses, 36-36 (1977)
3-Chloro-2-methylpropene.
IARC monographs on the evaluation of carcinogenic risks to humans, 63, 325-333 (1995-01-01)
3-Chloro-2-methylpropene.
Report on carcinogens : carcinogen profiles, 10, 57-58 (2004-08-24)
P C Chan et al.
Cancer research, 46(12 Pt 1), 6349-6352 (1986-12-01)
The carcinogenicity of 3-chloro-2-methylpropene (CMP), a chemical intermediate and insecticide, was studied because of possible human exposure and because of its structural relationship to vinyl chloride and allyl chloride. CMP in corn oil was administered by gavage to groups of

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