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Merck
CN
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文件

安全信息

107336

Sigma-Aldrich

2-硝基苄氯

99%

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别名:
α-氯-2-硝基甲苯
线性分子式:
O2NC6H4CH2Cl
CAS号:
612-23-7
分子量:
171.58
Beilstein:
388396
EC 号:
210-300-5
MDL编号:
MFCD00007185
UNSPSC代码:
12352100
PubChem化学物质编号:
24846764
NACRES:
NA.22

检测方案

99%

形式

solid

bp

127-133 °C/10 mmHg (lit.)

mp

46-48 °C (lit.)

溶解性

ethanol: soluble 98%

SMILES字符串

[O-][N+](=O)c1ccccc1CCl

InChI

1S/C7H6ClNO2/c8-5-6-3-1-2-4-7(6)9(10)11/h1-4H,5H2

InChI key

BXCBUWKTXLWPSB-UHFFFAOYSA-N

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应用

2-Nitrobenzyl chloride was used in the synthesis of S-(2-nitrobenzyl)cysteine which was inserted into human erythropoietin. 2-Nitrobenzyl chloride was used to prepare 4,4′-dinitrostillbene.

生化/生理作用

2-Nitrobenzyl chloride reacts with N-methyldiethanolamine and further reaction of the resulting quaternary diol with thionyl chloride at room temperature yields nitrobenzyl mustard quaternary salts.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

233.6 °F

闪点(°C)

112 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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Taek Jin Kang et al.
FEBS letters, 517(1-3), 211-214 (2002-06-14)
Using Escherichia coli cell-free protein synthesis system and aminoacylated amber suppressor tRNA, we successfully inserted an unnatural amino acid S-(2-nitrobenzyl)cysteine into human erythropoietin. Three different types of translation stop suppression were observed and each of the three types was easily
W A Denny et al.
International journal of radiation oncology, biology, physics, 29(2), 317-321 (1994-05-15)
To explore the utility of a new class of compounds, nitrobenzyl mustard quaternary salts, as hypoxia-selective prodrugs of diffusible cytotoxins. The parent compound N,N-bis(2-chloroethyl)-N-methyl-N-(2-nitrobenzyl)ammonium chloride (SN 25246) was prepared by reaction of 2-nitrobenzyl chloride with N-methyldiethanolamine, and reaction of the
Influence of steric effects on the excited triplet-state lifetime of 2, 2'-dinitrostilbene and 2, 2', 4, 4', 6, 6'-hexanitrostilbene in acetonitrile solution.
Smit KJ.
The Journal of Physical Chemistry, 96(16), 6555-6558 (1992)

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