106631
对甲基苯甲酰氯
98%
别名:
4-甲基苯甲酰氯
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关于此项目
线性分子式:
CH3C6H4COCl
化学文摘社编号:
分子量:
154.59
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-864-8
Beilstein/REAXYS Number:
471492
MDL number:
产品名称
对甲基苯甲酰氯, 98%
InChI key
NQUVCRCCRXRJCK-UHFFFAOYSA-N
InChI
1S/C8H7ClO/c1-6-2-4-7(5-3-6)8(9)10/h2-5H,1H3
SMILES string
Cc1ccc(cc1)C(Cl)=O
vapor density
5.33 (vs air)
vapor pressure
0.55 mmHg ( 20 °C)
assay
98%
expl. lim.
1.6 %, 117 °F
refractive index
n20/D 1.553 (lit.)
bp
225-227 °C (lit.)
95-96 °C/10 mmHg (lit.)
mp
−4-−2 °C (lit.)
density
1.169 g/mL at 25 °C (lit.)
functional group
acyl chloride
Quality Level
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Application
用 p -甲苯甲酰氯制备抗原，甲苯酰-酰胺-人血清白蛋白 。
General description
p -甲苯甲酰氯使用三氟乙酸官能化介孔 Zr-TMS 催化剂使甲苯发生苯甲酰化反应 。使用受阻格氏试剂 2,6-二甲基苯基溴化镁 ，可导致双吡咯甲烷 1,9-二酰基化。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
179.6 °F - closed cup
flash_point_c
82 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Sheng Tang et al.
Journal of chromatography. A, 1476, 53-62 (2016-11-20)
In order to comprehensively understand the influence of coordination of the substituent at 2-position with those at 3- and 6-positions on the properties of chitosan derivatives, a series of chitosan 3,6-bis(arylcarbamate)-2-(amide)s (CACAs) and the related chiral stationary phases (CSPs) were
Benzoylation of toluene with p-toluoyl chloride over triflic acid functionalized mesoporous Zr-TMS catalyst.
Landge SM, et al.
J. Mol. Catal. A: Chem., 213(2), 257-266 (2004)
M H Karol et al.
Clinical allergy, 10(1), 101-109 (1980-01-01)
Two antigens, both containing tolyl groups, were compared for ability to detect IgE antibodies in workers hypersensitive to toluene diisocyanate. One antigen, formed by reaction of p-tolyl isocyanate with human serum albumin, detected antibodies in each of ten hypersensitive workers.
Nearly Chromatography-Free Synthesis of the A3B-Porphyrin 5-(4-Hydroxymethylphenyl)-10, 15, 20-tri-p-tolylporphinatozinc (II).
Zaidi SHH, et al.
Organic Process Research & Development, 10(2), 304-314 (2006)
Komal M Vyas et al.
Chemico-biological interactions, 240, 250-266 (2015-09-06)
Pyrazolone based metal complexes have strong bio-activity but the anti-cancer mechanism of these derivatives is not fully understood. In recent years, Cu(II) complexes have attracted the interest of researchers increasingly because of their high antitumor activities that are usually related
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