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蒸汽密度
5.33 (vs air)
质量水平
蒸汽压
0.55 mmHg ( 20 °C)
方案
98%
expl. lim.
1.6 %, 117 °F
折射率
n20/D 1.553 (lit.)
沸点
225-227 °C (lit.)
95-96 °C/10 mmHg (lit.)
mp
−4-−2 °C (lit.)
密度
1.169 g/mL at 25 °C (lit.)
官能团
acyl chloride
SMILES字符串
Cc1ccc(cc1)C(Cl)=O
InChI
1S/C8H7ClO/c1-6-2-4-7(5-3-6)8(9)10/h2-5H,1H3
InChI key
NQUVCRCCRXRJCK-UHFFFAOYSA-N
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一般描述
p -甲苯甲酰氯使用三氟乙酸官能化介孔 Zr-TMS 催化剂使甲苯发生苯甲酰化反应 。使用受阻格氏试剂 2,6-二甲基苯基溴化镁 ，可导致双吡咯甲烷 1,9-二酰基化。
应用
用 p -甲苯甲酰氯制备抗原，甲苯酰-酰胺-人血清白蛋白 。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
179.6 °F - closed cup
闪点(°C)
82 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Sheng Tang et al.
Journal of chromatography. A, 1476, 53-62 (2016-11-20)
In order to comprehensively understand the influence of coordination of the substituent at 2-position with those at 3- and 6-positions on the properties of chitosan derivatives, a series of chitosan 3,6-bis(arylcarbamate)-2-(amide)s (CACAs) and the related chiral stationary phases (CSPs) were
Benzoylation of toluene with p-toluoyl chloride over triflic acid functionalized mesoporous Zr-TMS catalyst.
Landge SM, et al.
J. Mol. Catal. A: Chem., 213(2), 257-266 (2004)
Komal M Vyas et al.
Chemico-biological interactions, 240, 250-266 (2015-09-06)
Pyrazolone based metal complexes have strong bio-activity but the anti-cancer mechanism of these derivatives is not fully understood. In recent years, Cu(II) complexes have attracted the interest of researchers increasingly because of their high antitumor activities that are usually related
Nearly Chromatography-Free Synthesis of the A3B-Porphyrin 5-(4-Hydroxymethylphenyl)-10, 15, 20-tri-p-tolylporphinatozinc (II).
Zaidi SHH, et al.
Organic Process Research & Development, 10(2), 304-314 (2006)
M H Karol et al.
Clinical allergy, 10(1), 101-109 (1980-01-01)
Two antigens, both containing tolyl groups, were compared for ability to detect IgE antibodies in workers hypersensitive to toluene diisocyanate. One antigen, formed by reaction of p-tolyl isocyanate with human serum albumin, detected antibodies in each of ten hypersensitive workers.
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