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方案
95%
折射率
n20/D 1.434 (lit.)
沸点
125-128 °C (lit.)
密度
0.895 g/mL at 25 °C (lit.)
官能团
ketone
SMILES字符串
CC(=O)C1(C)CC1
InChI
1S/C6H10O/c1-5(7)6(2)3-4-6/h3-4H2,1-2H3
InChI key
OQBCJXUAQQMTRW-UHFFFAOYSA-N
一般描述
Methyl 1-methylcyclopropyl ketone undergoes samarium diiodide induced coupling to form 6-Hydroxy-3-methyl-6-(1-methylcyclopropyl)heptan-2-one.
Samarium Diiodide Induced Reactions of Cyclopropyl Ketones: Reductive Ring Cleavage and Dimerization Leading to 1, 8-Diketones-Scope, Limitations, Mechanisms.
Aulenta F, et al.
European Journal of Organic Chemistry, 2006(7), 1733-1739 (2006)
Valeriy V Pak et al.
Cell metabolism, 31(3), 642-653 (2020-03-05)
Hydrogen peroxide (H2O2) is a key redox intermediate generated within cells. Existing probes for H2O2 have not solved the problem of detection of the ultra-low concentrations of the oxidant: these reporters are not sensitive enough, or pH-dependent, or insufficiently bright
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