103799
五氟苯酚
≥99%, for peptide synthesis, ReagentPlus®
别名:
2,3,4,5,6-五氟苯酚
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关于此项目
线性分子式:
C6F5OH
化学文摘社编号:
分子量:
184.06
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352104
EC Number:
212-235-8
MDL number:
Beilstein/REAXYS Number:
1912584
产品名称
五氟苯酚, ReagentPlus®, ≥99%
InChI key
XBNGYFFABRKICK-UHFFFAOYSA-N
InChI
1S/C6HF5O/c7-1-2(8)4(10)6(12)5(11)3(1)9/h12H
SMILES string
Oc1c(F)c(F)c(F)c(F)c1F
product line
ReagentPlus®
assay
≥99%
form
solid
bp
143 °C (lit.)
mp
34-36 °C (lit.)
application(s)
peptide synthesis
functional group
fluoro
Quality Level
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Application
五氟苯酚可作为反应物与以下物质反应合成五氟苯基酯：
- 在二环己基碳二亚胺和乙酸乙酯存在的情况下与N-保护氨基酸反应。在1-乙基-(3-二甲基氨基丙基)碳酰二亚胺盐酸盐存在的情况下与
- 叔-丁氧羰基-L-丙氨酰甘氨酸反应。
- 在吡啶、二异丙基碳二亚胺和乙腈存在的情况下与脂肪族二羧酸反应。
General description
五氟苯酚被广泛用作溶液和固相肽合成的前体。 它也参与制备芳香族氟衍生物。.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
161.6 °F - closed cup
flash_point_c
72 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synthesis and Solid-state Conformations of 6S, 8aR/S-6-Alkyl-3, 3-dimethyltetrahydrooxazolo [3, 4-a] pyrazine-5, 8-diones (Pseudoproline Diketopiperazines)
Beauchard A, et al.
Indian Journal of Heterocyclic Chemistry, 28, 11-24 (2018)
Pentafluorophenol
Jones K
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Yutang Dai et al.
Macromolecular rapid communications, 35(15), 1326-1331 (2014-05-28)
Self-assembly of C3 discotic molecules bearing dipeptide pendants into helical supramolecular polymers is investigated. The dipeptides are constituted from glycine and alanine with altered sequence, aiming at modulating the steric hindrance and examining the steric effects on the assembly. This
Rens J Götz et al.
Chemical communications (Cambridge, England), (29)(29), 3384-3386 (2008-07-18)
The rational design of a ligand containing two electron-poor pi-rings, i.e. a triazine and a pentafluorophenoxy groups, has allowed the preparation of a copper complex where both the anticipated anion...pi interactions are present.
Nicolas Abello et al.
Analytical chemistry, 80(23), 9171-9180 (2008-10-29)
Stable isotope labeling (SIL) in combination with liquid chromatography-mass spectrometry is one of the most widely used quantitative analytical methods due to its sensitivity and ability to deal with extremely complex biological samples. However, SIL methods for metabolite analysis are
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