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Merck
CN

100331

Sigma-Aldrich

氯甲基甲醚

technical grade

别名:

MOM chloride, 氯甲氧基甲烷, 甲基氯甲醚

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About This Item

线性分子式:
ClCH2OCH3
CAS号:
分子量:
80.51
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22

等级

technical grade

质量水平

蒸汽压

3.55 psi ( 20 °C)

折射率

n20/D 1.396 (lit.)

沸点

55-57 °C (lit.)

密度

1.06 g/mL at 25 °C (lit.)

官能团

chloro
ether

储存温度

2-8°C

SMILES字符串

COCCl

InChI

1S/C2H5ClO/c1-4-2-3/h2H2,1H3

InChI key

XJUZRXYOEPSWMB-UHFFFAOYSA-N

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应用

Chloromethyl methyl ether (MOM-Cl) can be used as a reagent:
  •  For the introduction of the methoxymethyl (MOM) protecting group by converting alcohols to methoxy methyl (MOM) ethers.
  •  To prepare some methoxymethyl group containing metal complexes coordinated to carbonyl and dipyridyl ligands.        
  • In the preparation of fluorene/chloromethyl methyl ether cross-linked polymers by Friedel-Crafts polymerization.

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Flam. Liq. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

60.8 °F - closed cup

闪点(°C)

16 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

监管及禁止进口产品

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分析证书(COA)

Lot/Batch Number

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访问文档库

Bis(Chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 11, III56-III57 (2004-01-01)
Jung-Jae Lee et al.
Chemical communications (Cambridge, England), (15)(15), 1962-1963 (2009-04-01)
N-Alkylation of a fluorescent macrocyclic amine in aqueous micellar solution produces enhanced emission; the reaction with chloromethyl methyl ether exhibits autocatalysis.
Bis(chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 12, 71-73 (2011-08-19)
Martin A Berliner et al.
The Journal of organic chemistry, 70(23), 9618-9621 (2005-11-05)
[Reaction: see text]. Zinc(II) salts catalyze the reaction between acetals and acid halides to provide haloalkyl ethers in near-quantitative yield. Reactions from millimole to mole scale are typically complete in 1-4 h with 0.01 mol % catalyst. The solutions of
Synthesis and reactivity of new (methoxy) methyl complexes of manganese (I) and rhenium (I)
Hevia E, et al.
Organometallics, 25(20), 4909-4912 (2006)

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