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Merck
CN

100331

Sigma-Aldrich

氯甲基甲醚

technical grade

别名:

MOM chloride, 氯甲氧基甲烷, 甲基氯甲醚

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About This Item

线性分子式:
ClCH2OCH3
CAS号:
分子量:
80.51
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22

等级

technical grade

质量水平

蒸汽压

3.55 psi ( 20 °C)

方案

≥92.5%

表单

liquid

折射率

n20/D 1.396 (lit.)

沸点

55-57 °C ((lit.))
55-57 °C (lit.)

密度

1.06 g/mL at 25 °C (lit.)
1.06 g/mL at 25 °C

官能团

chloro
ether

储存温度

2-8°C

SMILES字符串

COCCl

InChI

[1S/C2H5ClO/c1-4-2-3/h2H2,1H3]
1S/C2H5ClO/c1-4-2-3/h2H2,1H3

InChI key

[XJUZRXYOEPSWMB-UHFFFAOYSA-N]
XJUZRXYOEPSWMB-UHFFFAOYSA-N

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应用

Chloromethyl methyl ether (MOM-Cl) can be used as a reagent:
  •  For the introduction of the methoxymethyl (MOM) protecting group by converting alcohols to methoxy methyl (MOM) ethers.
  •  To prepare some methoxymethyl group containing metal complexes coordinated to carbonyl and dipyridyl ligands.        
  • In the preparation of fluorene/chloromethyl methyl ether cross-linked polymers by Friedel-Crafts polymerization.

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Flam. Liq. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

60.8 °F - closed cup

闪点(°C)

16 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

监管及禁止进口产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Organometallics, 25, 4909-4909 (2006)
A Blair et al.
Cancer causes & control : CCC, 8(3), 473-490 (1997-05-01)
Epidemiologic evidence on the relation between reactive chemicals and cancer is reviewed. These highly reactive chemicals (acrylonitrile; bis[chloromethyl]ether and chloromethyl methyl ether; 1,3-butadiene, ethylene oxide; formaldehyde; mustard gas; sulfuric acid; and vinyl chloride) vary in use and exposure. All are
A modified low-cost preparation of chloromethyl methyl ether (MOM-Cl)
Reggelin M and Doerr S
Synlett, 2004(06), 1117-1117 (2004)
Friedel-Crafts polymerization of fluorene with methylene chloride, methoxyacetyl chloride, and chloromethyl methyl ether
Nystuen NJ and Jones MB
Journal of Polymer Science, 23(5), 1433-1444 (1985)
Synthesis and reactivity of new (methoxy) methyl complexes of manganese (I) and rhenium (I)
Hevia E, et al.
Organometallics, 25(20), 4909-4912 (2006)

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