100331
氯甲基甲醚
technical grade
别名:
MOM chloride, 氯甲氧基甲烷, 甲基氯甲醚
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线性分子式:
ClCH2OCH3
化学文摘社编号:
分子量:
80.51
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
EC Number:
203-480-1
MDL number:
产品名称
氯甲基甲醚, technical grade
InChI
[1S/C2H5ClO/c1-4-2-3/h2H2,1H3]
1S/C2H5ClO/c1-4-2-3/h2H2,1H3
InChI key
[XJUZRXYOEPSWMB-UHFFFAOYSA-N]
XJUZRXYOEPSWMB-UHFFFAOYSA-N
SMILES string
COCCl
grade
technical grade
vapor pressure
3.55 psi ( 20 °C)
assay
≥92.5%
form
liquid
refractive index
n20/D 1.396 (lit.)
bp
55-57 °C ((lit.))
55-57 °C (lit.)
density
1.06 g/mL at 25 °C (lit.)
1.06 g/mL at 25 °C
functional group
chloro
ether
storage temp.
2-8°C
Quality Level
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Application
Chloromethyl methyl ether (MOM-Cl) can be used as a reagent:
- For the introduction of the methoxymethyl (MOM) protecting group by converting alcohols to methoxy methyl (MOM) ethers.
- To prepare some methoxymethyl group containing metal complexes coordinated to carbonyl and dipyridyl ligands.
- In the preparation of fluorene/chloromethyl methyl ether cross-linked polymers by Friedel-Crafts polymerization.
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
监管及禁止进口产品
此项目有
Jung-Jae Lee et al.
Chemical communications (Cambridge, England), (15)(15), 1962-1963 (2009-04-01)
N-Alkylation of a fluorescent macrocyclic amine in aqueous micellar solution produces enhanced emission; the reaction with chloromethyl methyl ether exhibits autocatalysis.
Bis(Chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 11, III56-III57 (2004-01-01)
Synthesis and reactivity of new (methoxy) methyl complexes of manganese (I) and rhenium (I)
Hevia E, et al.
Organometallics, 25(20), 4909-4912 (2006)
Bis(chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 12, 71-73 (2011-08-19)
Martin A Berliner et al.
The Journal of organic chemistry, 70(23), 9618-9621 (2005-11-05)
[Reaction: see text]. Zinc(II) salts catalyze the reaction between acetals and acid halides to provide haloalkyl ethers in near-quantitative yield. Reactions from millimole to mole scale are typically complete in 1-4 h with 0.01 mol % catalyst. The solutions of
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