C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents.

C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents.

Chemical communications (Cambridge, England) (2002-10-26)

Nathalie Merceron, Antoine Baceiredo, Heinz Gornitzka, Guy Bertrand

摘要

C-Phosphanyl-C-chloroiminium salts formally react as phosphonio(amino)carbenes with tert-butyl isocyanide and trimethylphosphine, and as R2NC+ with vinyl ether and diisopropylamine.