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Chemoselective and regiospecific Suzuki coupling on a multisubstituted sp(3)-carbon in 1,1-diborylalkanes at room temperature.

Chemoselective and regiospecific Suzuki coupling on a multisubstituted sp(3)-carbon in 1,1-diborylalkanes at room temperature.

Journal of the American Chemical Society (2010-08-12)

Kohei Endo, Takahiro Ohkubo, Munenao Hirokami, Takanori Shibata

PMID20698667

摘要

The palladium-catalyzed Suzuki-Miyaura cross-coupling on a multisubstituted sp(3)-carbon in 1,1-diborylalkanes was achieved at room temperature. The generation of a monoborate intermediate by virtue of the adjacent B atom could result in the chemoselective coupling reaction under ambient conditions.

材料

货号

品牌

产品描述

676578

Sigma-Aldrich

双(三叔丁基膦)钯(0)

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