Bifluoride-catalysed sulfur(VI) fluoride exchange reaction for the synthesis of polysulfates and polysulfonates.

Bifluoride-catalysed sulfur(VI) fluoride exchange reaction for the synthesis of polysulfates and polysulfonates.

Nature chemistry (2017-10-25)

Bing Gao, Linda Zhang, Qinheng Zheng, Feng Zhou, Liana M Klivansky, Jianmei Lu, Yi Liu, Jiajia Dong, Peng Wu, K Barry Sharpless

PMID29064495

摘要

Polysulfates and polysulfonates possess exceptional mechanical properties making them potentially valuable engineering polymers. However, they have been little explored due to a lack of reliable synthetic access. Here we report bifluoride salts (Q