- In situ formation of ligand and catalyst--application in ruthenium-catalyzed enantioselective reduction of ketones.
In situ formation of ligand and catalyst--application in ruthenium-catalyzed enantioselective reduction of ketones.
Chemical communications (Cambridge, England) (2005-08-11)
Patrik Västilä, Jenny Wettergren, Hans Adolfsson
PMID16091792
摘要
The direct in situ formation of highly efficient ruthenium-catalysts for the asymmetric reduction of ketones was obtained by combining chiral ligand building blocks with a ruthenium precursor.