- Chemistry of single-walled carbon nanotubes.
Chemistry of single-walled carbon nanotubes.
Accounts of chemical research (2002-12-18)
S Niyogi, M A Hamon, H Hu, B Zhao, P Bhowmik, R Sen, M E Itkis, R C Haddon
PMID12484799
摘要
In this Account we highlight the experimental evidence in favor of our view that carbon nanotubes should be considered as a new macromolecular form of carbon with unique properties and with great potential for practical applications. We show that carbon nanotubes may take on properties that are normally associated with molecular species, such as solubility in organic solvents, solution-based chemical transformations, chromatography, and spectroscopy. It is already clear that the nascent field of nanotube chemistry will rival that of the fullerenes.
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碳纳米管,单壁,十八烷基胺官能化, 80-90% carbon basis, D × L 2-10 nm × 0.5-2 μm , bundle dimensions, avg. no. of layers, 1