sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

摘要

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

材料

货号

品牌

产品描述

510033

Sigma-Aldrich

Raney^®-镍, W.R. Grace and Co. Raney^® 2400, slurry, in H₂O, active catalyst

203904

Sigma-Aldrich

镍, powder, <150 μm, 99.99% trace metals basis

357634

Sigma-Aldrich

镍, wire, diam. 0.25 mm, ≥99.9%

268283

Sigma-Aldrich

镍, powder, <1 μm, 99.8% trace metals basis

357588

Sigma-Aldrich

镍, foil, thickness 0.1 mm, 99.98% trace metals basis

GF56791378

镍, pellets, 100g, max. size 10mm, 99.999%

267007

Sigma-Aldrich

镍, foil, thickness 0.25 mm, 99.995% trace metals basis

267074

Sigma-Aldrich

镍, rod, diam. 6.35 mm, ≥99.99% trace metals basis

767484

Sigma-Aldrich

镍, sputtering target, diam. × thickness 2.00 in. × 0.25 in., 99.95% trace metals basis

267058

Sigma-Aldrich

镍, wire, diam. 0.5 mm, ≥99.99% trace metals basis

357626

Sigma-Aldrich

镍, wire, diam. 0.5 mm, ≥99.9% trace metals basis

GF86063654

镍, foil, 100x100mm, thickness 1.6mm, 99%

GF17897596

镍, pellets, 100g, max. size 5mm, 99.99+%

GF18587975

镍, sphere, 100pcs, diameter 1.0mm, precision sphere grade 200, 99%

GF88290625

镍, foil, 100x100mm, thickness 0.25mm, annealed, 99%

GF60569455

镍, foil, 100x100mm, thickness 0.1mm, annealed, 99%

GF04391591

镍, mesh, 100x250mm, nominal aperture 0.73mm, wire diameter 0.25mm, 26x26 wires/inch, open area 55%, plain weave mesh, 99%

GF37939506

镍, mesh, 30x30mm, nominal aperture 0.34mm, thickness 0.025mm, wire diameter 0.041mm, 70 wires/inch, open area 80%, electro-formed mesh, 99.9%

GF21346848

镍, rod, 100mm, diameter 1.5mm, 99.99+%

GF11019697

镍, wire reel, 5m, diameter 0.025mm, as drawn, 99.6+%

GF27854196

镍, foil, 50x50mm, thickness 1.6mm, 99%

GF56481969

镍, pellets, 20g, max. size 5mm, 99.99+%

GF90261547

镍, mesh, 130x130mm, nominal aperture 0.04mm, thickness 0.004mm, wire diameter 0.011mm, 500 wires/inch, open area 60%, electro-formed mesh, 99.9%

GF89678570

镍, wire reel, 100m, diameter 0.025mm, as drawn, 99.98%

GF07235131

镍, mesh, 240x240mm, nominal aperture 0.43mm, thickness 0.004mm, wire diameter 0.067mm, 51 wires/inch, open area 75%, electro-formed mesh, 99.9%

GF03364499

镍, rod, 50mm, diameter 5.0mm, 99.99+%

GF12124460

镍, foil, not light tested, 50x50mm, thickness 0.00025mm, temporary acrylic support, 99.95%

GF38044627

镍, foil, 300x300mm, thickness 0.125mm, annealed, 99%

GF85317677

镍, foil, not light tested, 50x50mm, thickness 0.0005mm, temporary acrylic support, 99.95%

GF35122092

镍, mesh, 65x65mm, nominal aperture 0.04mm, thickness 0.004mm, wire diameter 0.011mm, 500 wires/inch, open area 60%, electro-formed mesh, 99.9%