Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands.

Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands.

Inorganic chemistry (2010-04-16)

Constantinos C Stoumpos, Ross Inglis, Olivier Roubeau, Harikleia Sartzi, Alexandros A Kitos, Constantinos J Milios, Guillem Aromí, Anastasios J Tasiopoulos, Vasilios Nastopoulos, Euan K Brechin, Spyros P Perlepes

PMID20392125

摘要

The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn(II)(4)Mn(III)Mn(IV)) or extremely rare (Mn(II)Mn(III)(5) and Mn(II)(3)Mn(III)(3)) metal oxidation-state combinations and uncommon structural motifs.