- A mild and catalyst-free conversion of solid phase benzylidenemalononitrile/benzylidenemalonate to N-benzylidene-amine and its application for fluorescence detection of primary alkyl amine vapor.
A mild and catalyst-free conversion of solid phase benzylidenemalononitrile/benzylidenemalonate to N-benzylidene-amine and its application for fluorescence detection of primary alkyl amine vapor.
Chemical communications (Cambridge, England) (2013-12-04)
Liqi Shi, Yanyan Fu, Chao He, Defeng Zhu, Yixun Gao, Yuerong Wang, Qingguo He, Huimin Cao, Jiangong Cheng
PMID24296866
摘要
A new rapid and catalyst-free solid/vapor reaction between benzylidenemalonate/benzylidenemalononitrile and primary alkyl amines was found. With these as sensory units of fluorescent polymers, probes for primary amine vapor with high sensitivity and selectivity were developed.
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