- Intramolecular dealkylation of chelating diamines with Ru(II) complexes.
Intramolecular dealkylation of chelating diamines with Ru(II) complexes.
Chemical communications (Cambridge, England) (2002-09-26)
M Esther Morilla, Galanda Morfes, M Carmen Nicasio, Tomás R Belderrain, M Mar Díaz-Requejo, Claudia Graiff, Antonio Tiripicchio, Roberto Sánchez-Delgado, Pedro J Pérez
PMID12271639
摘要
N,N, N',N'-Tetraethylethylenediamine undergoes simple or double intramolecular dealkylation reactions in the presence of the complexes [RuCl2(diene)]n (diene = cod, nbd) or trans-[RuCl2(diene)(morfoline)2 at 80 degrees C to afford chelating amine ligands which contains one or two N-H functionalities.
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