- Diversity-oriented synthesis of dibenzoazocines and dibenzoazepines via a microwave-assisted intramolecular A(3)-coupling reaction.
Diversity-oriented synthesis of dibenzoazocines and dibenzoazepines via a microwave-assisted intramolecular A(3)-coupling reaction.
Organic letters (2010-05-21)
Jitender B Bariwal, Denis S Ermolat'ev, Toma N Glasnov, Kristof Van Hecke, Vaibhav P Mehta, Luc Van Meervelt, C Oliver Kappe, Erik V Van der Eycken
PMID20481446
摘要
An unprecedented, diversity-oriented strategy for the generation of 6,7-dihydro-5H-dibenzo[c,e]azepines and 5,6,7,8-tetrahydrodibenzo[c,e]azocines by a microwave-assisted copper-catalyzed intramolecular A(3)-coupling reaction is presented.