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  • Folding-induced selective hydrogenation of helical 9,10-anthraquinone analogues.

Folding-induced selective hydrogenation of helical 9,10-anthraquinone analogues.

Organic letters (2008-10-11)
Hai-Yu Hu, Jun-Feng Xiang, Jing Cao, Chuan-Feng Chen
摘要

The first selective catalytic hydrogenation induced by the artificial helix based on oligo(phenanthroline dicarboxamide)s containing a 9,10-anthraquinone subunit is described. Due to the steric hindrance within the helically folded oligomers, the selective reductions of the anthraquinone units were completely different from those of model substrates, which subsequently mimicked the enzyme catalysis for preventing some reactions from occurring.

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Supelco
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货号包装规格是否有货价格数量
5 mL
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CN¥1,649.70
10 x 0.75 mL
预计发货时间 March 03, 2025
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CN¥2,396.87
25 mL
预计发货时间 March 03, 2025
详情...
CN¥4,878.66