804975
DTBPF-Pd-G3
Synonym(s):
1,1′-Bis(di-tert-butylphosphino)ferrocene Pd G3
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¥5,685.79
Estimated to ship on2025年5月06日Details
Select a Size
About This Item
¥5,685.79
Estimated to ship on2025年5月06日Details
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![[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98%](/deepweb/assets/sigmaaldrich/product/structures/192/459/02d1239c-1119-49d9-b392-a04d8f53855c/640/02d1239c-1119-49d9-b392-a04d8f53855c.png)
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form
solid
Quality Level
feature
generation 3
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
impurities
may contain 10-20% Di-μ-mesylbis[2′-(amino-N)[1,1′-biphenyl]-2-yl-C]dipalladium(II) (Aldrich Number 762156)
may contain 5-10% DTBPF (Aldrich Number 695149)
may contain 5-10% pentane
mp
87-150 °C (decomposition)
functional group
phosphine
InChI
1S/2C13H22P.C12H10N.CH4O3S.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1
InChI key
AGXLTHQKOWPGBX-UHFFFAOYSA-M
1 of 4
This Item | 806811 | 806900 | 806765 |
|---|---|---|---|
| form mesoporous, powder | form powder | form mesoporous, powder | form mesoporous, powder |
| assay 99.9% trace metals basis | assay 99.9% trace metals basis | assay 99.9% trace metals basis | assay 99.9% trace metals basis |
| particle size 1 μm | particle size 1 μm | particle size 2 μm | particle size 3 μm |
| mp >1600 °C (lit.) | mp >1600 °C (lit.) | mp >1600 °C (lit.) | mp >1600 °C (lit.) |
| surface area 300-400 m2/g | surface area 1000 ± 100 m2/g | surface area 300-400 m2/g | surface area - |
| pore size 0.2-0.4 cm3/g pore volume | pore size 0.1-0.3 cm3/g pore volume, 1.9-2.3 nm pore diameter, ~2 nm pore size | pore size 0.2-0.4 cm3/g pore volume, ~4 nm pore size | pore size 0.1-0.3 cm3/g pore volume, ~2 nm pore size |
General description
Application
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Articles
G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
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