222380
Allylpalladium(II) chloride dimer
98%
Synonym(s):
Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium, [PdCl(C3H5)]2
About This Item
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Quality Level
Assay
98%
form
solid
reaction suitability
core: palladium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
greener alternative category
, Aligned
storage temp.
2-8°C
SMILES string
Cl[Pd]CC=C.Cl[Pd]CC=C
InChI
1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
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This Item | 49728 | 30674 | 42424 |
|---|---|---|---|
| fluorescence λex 617 nm; λem 641 nm in 0.1 M phosphate pH 7.0 | fluorescence λex 619 nm; λem 643 nm in 0.1 M phosphate pH 7.0 | fluorescence λex 681 nm; λem 714 nm in 0.1 M phosphate pH 7.0 | fluorescence - |
| form powder | form solid | form - | form powder |
| storage temp. −20°C | storage temp. −20°C | storage temp. −20°C | storage temp. −20°C |
| assay ≥90% (HPCE) | assay ≥80% (coupling to thiols) | assay ≥90.0% (HPCE) | assay ≥90% (HPLC) |
| product line BioReagent | product line - | product line BioReagent | product line - |
General description
Application
- Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.[2]
- Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.[3]
- Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.[4]
- As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
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Articles
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
Protocols
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
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