87751
Diamide
≥99.0% (CHN)
Synonym(s):
1,1′-Azobis(N,N-dimethylformamide), N,N,N′,N′-Tetramethylazodicarboxamide, Azodicarboxylic acid bis(dimethylamide), Diazenedicarboxylic acid bis(N,N-dimethylamide), TMAD
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About This Item
Linear Formula:
(CH3)2NCON=NCON(CH3)2
CAS Number:
Molecular Weight:
172.19
EC Number:
233-951-7
UNSPSC Code:
12352202
PubChem Substance ID:
Beilstein/REAXYS Number:
1910409
MDL number:
InChI key
VLSDXINSOMDCBK-BQYQJAHWSA-N
InChI
1S/C6H12N4O2/c1-9(2)5(11)7-8-6(12)10(3)4/h1-4H3/b8-7+
SMILES string
CN(C)C(=O)\N=N\C(=O)N(C)C
assay
≥99.0% (CHN)
form
crystalline
color
yellow
storage temp.
−20°C
Other Notes
Reagent for Mitsunobu reactions of acids with high pK′s ; synthesis of cyclic ethers from diols
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Tatiana Rochat et al.
Nucleic acids research, 40(19), 9571-9583 (2012-08-21)
The transcriptional regulator Spx plays a key role in maintaining the redox homeostasis of Bacillus subtilis cells exposed to disulfide stress. Defects in Spx were previously shown to lead to differential expression of numerous genes but direct and indirect regulatory
T. Tsunoda et al.
Chemistry Letters (Jpn), 539-539 (1994)
S. Harusawa et al.
Tetrahedron Letters, 37, 2463 -2463 (1996)
Yong Tao et al.
Insect biochemistry and molecular biology, 43(9), 820-828 (2013-06-29)
Anthranilic diamides, which include the new commercial insecticide, chlorantraniliprole, are an exciting new class of chemistry that target insect ryanodine receptors. These receptors regulate release of stored intracellular calcium and play a critical role in muscle contraction. As with insects
Dierk-Christoph Pöther et al.
International journal of medical microbiology : IJMM, 303(3), 114-123 (2013-03-23)
Bacillithiol (Cys-GlcN-malate, BSH) serves as a major low molecular weight thiol in low GC Gram-positive bacteria including Bacillus species and a variety of Staphylococcus aureus strains. These bacteria do not produce glutathione (GSH). In this study, HPLC analyses were used
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