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Tetrabutylammonium hydroxide solution

~40% in water, suitable for ion chromatography

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N(OH)
CAS Number:
Molecular Weight:
259.47
Beilstein:
3571228
MDL number:
UNSPSC Code:
12000000
PubChem Substance ID:
NACRES:
NB.21

description

cationic

Quality Level

form

liquid

concentration

~40% in water

technique(s)

ion chromatography: suitable

impurities

≤0.01% halides (as bromide)

density

0.995 g/cm3

anion traces

sulfate (SO42-): ≤100 mg/kg

cation traces

K: ≤100 mg/kg
Na: ≤100 mg/kg

SMILES string

[OH-].CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H2/q+1;/p-1

InChI key

VDZOOKBUILJEDG-UHFFFAOYSA-M

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General description

Tetrabutylammonium hydroxide (TBAOH) is a quaternary ammonium salt,mainly used as a strong base and phase-transfer catalyst.

Application

TBAOH may be used as an ion-pairing reagent in mobile phase preparation for reverse phase ion-pair high performance liquid chromatography during chromium (III) and chromium (VI) determination.

Caution

may crystallize; can be redissolved on heating (max. 40°C)

Linkage

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Other Notes

Reagent suitable for use in ion chromatography

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Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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P.R. Haddad et al.
Ion Chromatography: Principles and Applications null
Simultaneous determination of chromium (III) and chromium (VI) with reversed-phase ion-pair high-performance liquid chromatography.
Jen, Jen-Fon, et al.
Analyst, 118.10 , 1281-1284 (1993)
T. Tang et al.
Microchemical Journal, Devoted to the Application of Microtechniques in All Branches of Science, 45, 58-58 (1992)
Liwen Zhang et al.
ACS nano, 8(12), 12250-12258 (2014-11-18)
Photothermal therapy (PTT) is an emerging treatment modality that is under intensive preclinical investigations for the treatment of various medical conditions, including cancer. However, the lack of targeting function of PTT agents hampers its clinical application. An effective and nontoxic
David J Posson et al.
Nature structural & molecular biology, 20(2), 159-166 (2012-12-25)
Understanding how ion channels open and close their pores is crucial for comprehending their physiological roles. We used intracellular quaternary ammonium blockers, electrophysiology and X-ray crystallography to locate the voltage-dependent gate in MthK potassium channels from Methanobacterium thermoautotrophicum. Blockers bind

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