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Merck
CN

50439

Perchloric acid

0.01 M HClO4 in water (0.01N), eluent for IC

Synonym(s):

Perchloric acid solution

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About This Item

Linear Formula:
HClO4
CAS Number:
Molecular Weight:
100.46
NACRES:
NB.21
PubChem Substance ID:
UNSPSC Code:
12161700
MDL number:
Concentration:
0.01 M HClO4 in water (0.01N)
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Product Name

Perchloric acid, 0.01 M HClO4 in water (0.01N), eluent for IC

InChI

1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)

SMILES string

OCl(=O)(=O)=O

InChI key

VLTRZXGMWDSKGL-UHFFFAOYSA-N

concentration

0.01 M HClO4 in water (0.01N)

technique(s)

ion chromatography: suitable

Quality Level

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Application

Metrohm IC Application note AN-O-039 :Organic acids in samples from biogas production by ion-exclusion chromatography after dialysis

Metrohm IC Application note AN-O-040 :Borate in seawater

Metrohm IC Application note AN-S-281 :Inorganic and organic anions in wine applying Inline Ultrafiltration

General description

This eluent for ion chromatography is determined by potentiometric titration. Content and expiry date can be found on the certificate.

Other Notes

Visit the IC Portal to learn more

Preparation Note

Prepared with perchloric acid and high purity water (18.2 MΩ, 0.2 μm filtered)

Storage Class

12 - Non Combustible Liquids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

Regulatory Information

易制爆化学品
危险化学品
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Dipanwita Das et al.
Journal of the American Chemical Society, 135(10), 4018-4026 (2013-02-28)
Catalytic four-electron reduction of O2 by ferrocene (Fc) and 1,1'-dimethylferrocene (Me2Fc) occurs efficiently with a dinuclear copper(II) complex [Cu(II)2(XYLO)(OH)](2+) (1), where XYLO is a m-xylene-linked bis[(2-(2-pyridyl)ethyl)amine] dinucleating ligand with copper-bridging phenolate moiety], in the presence of perchloric acid (HClO4) in
Dipanwita Das et al.
Journal of the American Chemical Society, 135(7), 2825-2834 (2013-02-12)
Selective two-electron plus two-proton (2e(-)/2H(+)) reduction of O(2) to hydrogen peroxide by ferrocene (Fc) or 1,1'-dimethylferrocene (Me(2)Fc) in the presence of perchloric acid is catalyzed efficiently by a mononuclear copper(II) complex, [Cu(II)(tepa)](2+) (1; tepa = tris[2-(2-pyridyl)ethyl]amine) in acetone. The E(1/2)
He-Ping Zhao et al.
Environmental science & technology, 47(3), 1565-1572 (2013-01-10)
We evaluated a strategy for achieving complete reduction of perchlorate (ClO(4)(-)) in the presence of much higher concentrations of sulfate (SO(4)(2-)) and nitrate (NO(3)(-)) in a hydrogen-based membrane biofilm reactor (MBfR). Full ClO(4)(-) reduction was achieved by using a two-stage
Martin G Liebensteiner et al.
Science (New York, N.Y.), 340(6128), 85-87 (2013-04-06)
Perchlorate and chlorate anions [(per)chlorate] exist in the environment from natural and anthropogenic sources, where they can serve as electron acceptors for bacteria. We performed growth experiments combined with genomic and proteomic analyses of the hyperthermophile Archaeoglobus fulgidus that show
Christine M Beavers et al.
Inorganic chemistry, 52(4), 1670-1672 (2013-01-29)
The reaction of 2-pyridylphosphonic acid (LH(2)) with iron(II) perchlorate and iron(III) nitrate afforded an interconnected, double-layered, cationic iron cage, [{Fe(36)L(44)(H(2)O)(48)}](20+) (1a), the largest interconnected, polynuclear ferric cage reported to date. Magnetic studies on 1a revealed antiferromagnetic coupling between the spins

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