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686085

Sigma-Aldrich

Titanium(III) chloride

hydrogen-storage grade, ≥99.99%

Synonym(s):

Titanium trichloride

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About This Item

Linear Formula:
TiCl3
CAS Number:
Molecular Weight:
154.23
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
Assay:
≥99.99%
grade:
hydrogen-storage grade
form:
crystals

grade

hydrogen-storage grade

Assay

≥99.99%

form

crystals

mp

440 °C (dec.) (lit.)

SMILES string

Cl[Ti](Cl)Cl

InChI

1S/3ClH.Ti/h3*1H;/q;;;+3/p-3

InChI key

YONPGGFAJWQGJC-UHFFFAOYSA-K

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Application

Used for the vapor-phase formation of intermetallic compounds with ultrafine particle size.

Analysis Note

XRD plots and metal purity data are available upon request.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Pyr. Sol. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Gnana S Siluvai et al.
Biochemistry, 48(51), 12133-12144 (2009-11-20)
Sco-like proteins contain copper bound by two cysteines and a histidine residue. Although their function is still incompletely understood, there is a clear involvement with the assembly of cytochrome oxidases that contain the Cu(A) center in subunit 2, possibly mediating
D J Kushner et al.
Analytical biochemistry, 133(1), 116-119 (1983-08-01)
Hydroxamic acid siderophores were observed to be inactivated by exposure to titanium(III) chloride. To study the reaction, a series of eight model hydroxamic acids were prepared and reacted with titanium(III) chloride. The products were shown by ir and NMR comparisons
Yan Zhang et al.
Organic & biomolecular chemistry, 9(13), 4977-4982 (2011-05-21)
N-N bond cleavage in hydrazines is widely used in the preparation of amines and thus occupies a significant place in organic synthesis. In this paper, we report a new method for the reductive cleavage of N-N bonds in hydrazines by
C P Offen et al.
Xenobiotica; the fate of foreign compounds in biological systems, 15(6), 503-511 (1985-06-01)
The metabolic fate of chlormethiazole in healthy male subjects has been investigated following the oral administration of a single dose of chlormethiazole edisylate. Five urinary C-oxidation metabolites were identified and shown to be identical with previously reported metabolites. A novel
Catalytic oxidation of hydrazo derivatives promoted by a TiCl3/HBr system.
Eyal Drug et al.
Journal of the American Chemical Society, 129(45), 13784-13785 (2007-10-26)

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