686085
Titanium(III) chloride
hydrogen-storage grade, ≥99.99%
Synonym(s):
Titanium trichloride
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About This Item
Linear Formula:
TiCl3
CAS Number:
Molecular Weight:
154.23
UNSPSC Code:
26111700
PubChem Substance ID:
EC Number:
231-728-9
MDL number:
Assay:
≥99.99%
Grade:
hydrogen-storage grade
Form:
crystals
InChI key
YONPGGFAJWQGJC-UHFFFAOYSA-K
InChI
1S/3ClH.Ti/h3*1H;/q;;;+3/p-3
SMILES string
Cl[Ti](Cl)Cl
grade
hydrogen-storage grade
assay
≥99.99%
form
crystals
mp
440 °C (dec.) (lit.)
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Application
Used for the vapor-phase formation of intermetallic compounds with ultrafine particle size.
Analysis Note
XRD plots and metal purity data are available upon request.
signalword
Danger
hcodes
Hazard Classifications
Pyr. Sol. 1 - Skin Corr. 1B
supp_hazards
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Gnana S Siluvai et al.
Biochemistry, 48(51), 12133-12144 (2009-11-20)
Sco-like proteins contain copper bound by two cysteines and a histidine residue. Although their function is still incompletely understood, there is a clear involvement with the assembly of cytochrome oxidases that contain the Cu(A) center in subunit 2, possibly mediating
Jun-ichi Matsuo et al.
Organic letters, 12(14), 3266-3268 (2010-06-24)
N-p-Toluenesulfonyl (Ts) aldimines reacted with 3-ethoxycyclobutanones by catalysis of titanium(IV) chloride to afford 2,3-di- or 2,3,3-trisubstituted N-Ts-2,3-dihydro-4-pyridones. Synthesis of (+/-)-bremazocine was efficiently accomplished by using this method.
Gema Ruano et al.
The Journal of organic chemistry, 68(5), 2024-2027 (2003-03-01)
Enantiomerically pure N-substituted epoxyalkene-2-azetidinones reacted with titanocene monochloride to give stereospecifically polyfunctionalized bicyclic beta-lactams. Four isomeric epoxyaldehydes 2 reacted with TiCp2Cl to give exclusively the respective carbacephams 7 while under the same reaction conditions the epoxyesters 1, which are more
H A Akers et al.
Analytical biochemistry, 154(2), 559-563 (1986-05-01)
Thirteen model alpha-ketocarboxylic acids and alpha-dicarbonyl compounds have been observed to be reduced by titanium(III) chloride. The products of these reactions were shown by melting (boiling) points, mixed melting points, derivatives, refractive indices, infrared, and NMR comparisons with authentic compounds
Kuo-Hui Lin et al.
Journal of agricultural and food chemistry, 59(7), 3420-3428 (2011-03-05)
The areca nut is the most widely consumed psychoactive substance in Taiwan, India, and Southeast Asia. It is considered to be an environmental risk factor for the development of oral submucous fibrosis and cancer. Arecoline, the major alkaloid of areca
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