All Photos(1)
Synonym(s):
Titanium trichloride
Linear Formula:
TiCl3
CAS Number:
Molecular Weight:
154.23
EC Number:
MDL number:
UNSPSC Code:
12352301
PubChem Substance ID:
Recommended Products
product line
ReagentPlus®
form
powder
reaction suitability
reagent type: catalyst
core: titanium
mp
440 °C (dec.) (lit.)
SMILES string
Cl[Ti](Cl)Cl
InChI
1S/3ClH.Ti/h3*1H;/q;;;+3/p-3
InChI key
YONPGGFAJWQGJC-UHFFFAOYSA-K
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Application
Used for the vapor-phase formation of intermetallic compounds with ultrafine particle size.
Used with tert-butylhydroperoxide in an alcoholic solvent to promote the reductive coupling of aryl aldehydes to 1,2-diols.
Catalyst for:
hydrogen desorption properties
Nitrogen-nitrogen reductive bond cleavage
Reagent for photocatalyst synthesis
Precursor for the preparation of nanostructures titania/cetyltrimethyammonium bromide nanoskeletons
Catalyst for:
hydrogen desorption properties
Nitrogen-nitrogen reductive bond cleavage
Reagent for photocatalyst synthesis
Precursor for the preparation of nanostructures titania/cetyltrimethyammonium bromide nanoskeletons
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Pyr. Sol. 1 - Skin Corr. 1B
Supplementary Hazards
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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European Journal of Organic Chemistry, 4050-4050 (2007)
S. Isobe, et al.,
Applied Physics Letters, 99 (2011)
Shuxi Dai et al.
Nanoscale research letters, 5(11), 1829-1835 (2010-12-03)
Highly crystalline TiO(2) nanostructures were prepared through a facile inorganic acid-assisted hydrothermal treatment of hexagonal-structured assemblies of nanocrystalline titiania templated by cetyltrimethylammonium bromide (Hex-ncTiO(2)/CTAB Nanoskeleton) as starting materials. All samples were characterized by X-ray diffraction (XRD) and transmission electron microscopy
D. Meroni, et al
Catalysis Today, 161, 169-174 (2011)
Jun-ichi Matsuo et al.
Organic letters, 12(14), 3266-3268 (2010-06-24)
N-p-Toluenesulfonyl (Ts) aldimines reacted with 3-ethoxycyclobutanones by catalysis of titanium(IV) chloride to afford 2,3-di- or 2,3,3-trisubstituted N-Ts-2,3-dihydro-4-pyridones. Synthesis of (+/-)-bremazocine was efficiently accomplished by using this method.
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