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Merck
CN

395404

Titanium(IV) chloride tetrahydrofuran complex

97%

Synonym(s):

Tetrachlorobis(tetrahydrofuran)titanium

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About This Item

Linear Formula:
TiCl4 · 2THF
CAS Number:
Molecular Weight:
333.89
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352106
MDL number:
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Product Name

Titanium(IV) chloride tetrahydrofuran complex, 97%

InChI

1S/2C4H8O.4ClH.Ti/c2*1-2-4-5-3-1;;;;;/h2*1-4H2;4*1H;/q;;;;;;+4/p-4

SMILES string

Cl[Ti](Cl)(Cl)Cl.C1CCOC1.C2CCOC2

InChI key

LXWBMENBONGPSB-UHFFFAOYSA-J

assay

97%

reaction suitability

core: titanium
reagent type: Lewis acid
reagent type: catalyst

mp

126-128 °C (lit.)

functional group

ether

storage temp.

2-8°C

Quality Level

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Application

Titanium(IV) chloride tetrahydrofuran complex can be used as a catalyst in intermolecular hydroamination reactions.

General description

Titanium(IV) chloride tetrahydrofuran complex, also known as TiCl4-THF, is a commonly used reagent in organic synthesis due to its Lewis acidic properties. It is used as a catalyst in various Friedel-Crafts reactions for the synthesis of aromatic compounds.

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B

supp_hazards

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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