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Sigma-Aldrich

Titanium(IV) chloride tetrahydrofuran complex

97%

Synonym(s):

Tetrachlorobis(tetrahydrofuran)titanium

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About This Item

Linear Formula:
TiCl4 · 2THF
CAS Number:
Molecular Weight:
333.89
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

reaction suitability

core: titanium
reagent type: Lewis acid
reagent type: catalyst

mp

126-128 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Ti](Cl)(Cl)Cl.C1CCOC1.C2CCOC2

InChI

1S/2C4H8O.4ClH.Ti/c2*1-2-4-5-3-1;;;;;/h2*1-4H2;4*1H;/q;;;;;;+4/p-4

InChI key

LXWBMENBONGPSB-UHFFFAOYSA-J

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General description

Titanium(IV) chloride tetrahydrofuran complex, also known as TiCl4-THF, is a commonly used reagent in organic synthesis due to its Lewis acidic properties. It is used as a catalyst in various Friedel-Crafts reactions for the synthesis of aromatic compounds.

Application

Titanium(IV) chloride tetrahydrofuran complex can be used as a catalyst in intermolecular hydroamination reactions.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B

Supplementary Hazards

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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