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Safety Information

201197

Sigma-Aldrich

Beryllium chloride

purified by sublimation, 99%

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About This Item

Empirical Formula (Hill Notation):
BeCl2
CAS Number:
Molecular Weight:
79.92
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:

Assay

99%

purified by

sublimation

mp

399 °C (lit.)

density

1.899 g/mL at 25 °C (lit.)

SMILES string

Cl[Be]Cl

InChI

1S/Be.2ClH/h;2*1H/q+2;;/p-2

InChI key

LWBPNIJBHRISSS-UHFFFAOYSA-L

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Application

Starting material for novel sterically encumbered arylberyllium compounds.

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

Target Organs

Respiratory system, Skin,Respiratory Tract

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Christian Strupp
The Annals of occupational hygiene, 55(1), 30-42 (2011-01-05)
The toxicity of soluble metal compounds is often different from that of the parent metal. Since no reliable data on acute toxicity, local effects, and mutagenicity of beryllium metal have ever been generated, beryllium metal powder was tested according to
K Eskandari
Journal of molecular modeling, 18(8), 3481-3487 (2012-01-31)
The nature of beryllium bonds formed between BeX2 (X is H, F and Cl) and some Lewis bases have been investigated. The distribution of the Laplacian of electron density shows that there is a region of charge depletion around the
T Sakaguchi et al.
Journal of toxicology and environmental health, 39(4), 517-526 (1993-08-01)
A 7BeCl2 solution containing 0.5 micrograms Be per mouse was injected subcutaneously, intraperitoneally, intramuscularly, intrathoracically, and intravenously, and distribution was observed for periods up to 1 wk. 7Be was excreted more rapidly following intravenous injection than by the other routes
C F Teixeira et al.
Toxicology, 61(3), 293-301 (1990-04-30)
A single i.v. dose (0.1 mmol Be2+/kg) of beryllium chloride prolonged the duration of pentobarbital-induced sleep and zoxazolamine-induced paralysis, in rats. The effects are correlated with changes of the pharmacokinetic parameters and with the in vitro inhibition of both aliphatic
Dmitry A Rozmanov et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 62(1-3), 92-96 (2005-11-01)
The experimental Raman vibrational spectrum of the 5.94 m water solution of the beryllium(II) chloride has been acquired. Theoretical frequencies, infrared and Raman intensities of the vibrational spectrum of the beryllium cation tetrahydrate have been calculated by means of quantum

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