10439-U
Carbopack™ Carbon Adsorbent
matrix Carbopack™ X, 120-400 mesh, bottle of 50 g
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About This Item
product name
Carbopack™ Adsorbent, matrix Carbopack™ X, 120-400 mesh, bottle of 50 g
product line
Carbopack™
Quality Level
form
granular
packaging
bottle of 50 g
technique(s)
LPLC: suitable
surface area
~240 m2/g
matrix
Carbopack™ X
matrix active group
carbon
particle size
120-400 mesh
pore size
~0.62 cm3/g mesoporosity
~0 cm3/g macroporosity
~0 cm3/g microporosity
~100 Å pore diameter
density
~0.39 g/mL (free fall density)
separation technique
reversed phase
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General description
Carbotrap® X has a very high specific surface area and was used for the recovery of low boiling hydrocarbons like 1,3-butadiene and isoprene.
Carbotrap®/Carbopack™ adsorbent can withstand high bake-out temperature without losing the mechanical and chemical integrity. It has a high affinity for isoprene and does not retain significant amounts of water. Furthermore it has a tendency to pulverize if it is packed too tightly.
A graphitized carbon black (GCB) can be non-porous or porous. The graphitization process results in a highly pure surface with great adsorption and desorption (if required) properties. Surface interactions depend solely on dispersion (London) forces. These particles are:
Generally, GCB adsorbents offer weaker relative adsorptive strength compared to carbon molecular sieve (CMS) adsorbents, and similar relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) adsorbents. Our Carbopack products are a type of GCB adsorbent.
For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon
- Granular
- Friable
- Used for molecules with an analyte size relative to C3-C20+ n-alkanes
- Hydrophobic (can be used in high humidity environments)
Generally, GCB adsorbents offer weaker relative adsorptive strength compared to carbon molecular sieve (CMS) adsorbents, and similar relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) adsorbents. Our Carbopack products are a type of GCB adsorbent.
- Particles are 40 mesh and smaller
- Use 40/60 mesh to prevent channeling (if observed with a 20/40 mesh Carbotrap® adsorbent)
- Use smaller mesh (60/80, 80/100, etc.) for all other applications
- Use the smallest particle size available as long as the application can handle the pressure drop
For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon
Legal Information
Carbopack is a trademark of Merck KGaA, Darmstadt, Germany
Carbotrap is a registered trademark of Merck KGaA, Darmstadt, Germany
WGK
nwg
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Stability of reactive low boiling hydrocarbons on carbon based adsorbents typically used for adsorptive enrichment and thermal desorption.
Dettmer K, et al.
Fresenius Journal of Analytical Chemistry, 366 (1), 70-78 (2000)
Comparison of Tenax TA and Carbotrap for sampling and analysis of volatile organic compounds in air.
Rothweiler H, et al.
Atmospheric Environment, 25 (2), 231-235 (1991)
Li-Ming Yuan et al.
Analytical chemistry, 78(18), 6384-6390 (2006-09-15)
Single-walled carbon nanotubes (SWNTs) have high surface area, high adsorption ability, and nanoscale interactions. In this study, capillary columns including SWNTs, ionic liquid (IL), and IL + SWNTs for GC were prepared. The separation results showed that SWNTs possessed a
Rybolt et al.
Journal of colloid and interface science, 220(1), 148-156 (1999-11-07)
Second gas-solid virial coefficients were determined at 403.5 +/- 0.5 K for 6 adsorbates, including butane, chloroform, trichlorofluoromethane (Freon 11), bromochloromethane, 1-chloro-2-methylpropane, and dibromodifluoromethane. For another 11 adsorbates, including dichlorodifluoromethane (Freon 12), chlorodifluoromethane (Freon 22), methyl chloride, methylene chloride, propane
Bikram Subedi et al.
Bulletin of environmental contamination and toxicology, 92(4), 460-465 (2013-12-10)
A selective pressurized liquid extraction technique (SPLE) was developed for the analysis of polychlorodibenzo-p-dioxins, polychlorodibenzofurans (PCDD/Fs) and dioxin-like polychlorobiphenyls (dl-PCBs) in clam and crab tissue. The SPLE incorporated multiple cleanup adsorbents (alumina, florisil, silica gel, celite, and carbopack) within the
Articles
Synthetic CMS carbons offer tailored adsorbents for specific applications.
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